| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Frégnaux, Mathieu
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2024Fine tuning of Nb-incorporated TiO2 thin films by atomic layer deposition and application as efficient electron transport layer in perovskite solar cellscitations
- 2024Fine tuning of Nb-incorporated TiO2 thin films by atomic layer deposition and application as efficient electron transport layer in perovskite solar cellscitations
- 2024Breaking 1.7 V Open Circuit Voltage in Large Area Transparent Perovskite Solar Cells Using Interfaces Passivationcitations
- 2024Interface defect formation for atomic layer deposition of SnO2 on metal halide perovskitescitations
- 2024Breaking 1.7 V Open Circuit Voltage in Large Area Transparent Perovskite Solar Cells Using Interfaces Passivationcitations
- 2024In situ evaluation of the strontium vandate oxide reactivity by NAP-XPS
- 2023Influence of X-Ray Irradiation During Photoemission Studies on Halide Perovskite-Based Devicescitations
- 2023Elucidating Interfacial Limitations Induced by Tin Oxide Electron Selective Layer Grown by Atomic Layer Deposition in N−I−P Perovskite-Based Solar Cellscitations
- 2023Breaking 1.7V open circuit voltage in large area transparent perovskite solar cells using bulk and interfaces passivation.citations
- 2023Formation and Etching of the Insulating Sr‐Rich V 5+ Phase at the Metallic SrVO 3 Surface Revealed by Operando XAS Spectroscopy Characterizationscitations
- 2023Formation and Etching of the Insulating Sr‐Rich V<sup>5+</sup> Phase at the Metallic SrVO<sub>3</sub> Surface Revealed by Operando XAS Spectroscopy Characterizationscitations
- 2022Photocatalytic nanocomposite anatase–rutile TiO2 coatingcitations
- 2022Photocatalytic nanocomposite anatase–rutile TiO2 coatingcitations
- 2022On the equilibrium electrostatic potential and light-induced charge redistribution in halide perovskite structurescitations
- 2022Oxide thin film depth profiling: interest and limitations of argon sputtering for photoemission spectroscopy
- 2021Carrier gradients and the role of charge selective contacts in lateral heterojunction all back contact perovskite solar cellscitations
- 2021XPS monitoring of SrVO3 thin films from demixing to air ageing: The asset of treatment in watercitations
- 2021Highly Transparent and Conductive Indium‐Free Vanadates Crystallized at Reduced Temperature on Glass Using a 2D Transparent Nanosheet Seed Layercitations
- 2020Improving the Activity of Fe/C/N ORR Electrocatalyst Using Double Ammonia Promoted CO2 Laser Pyrolysis
- 2020Three dimensional resistance mapping of self-organized Sr3V2O8 nanorods on metallic perovskite SrVO3 matrixcitations
- 2020Transfer of Epitaxial SrTiO 3 Nanothick Layers Using Water-Soluble Sacrificial Perovskite Oxidescitations
- 2018Synthesis and characterization of Carbon/Nitrogen/Iron based nanoparticles by laser pyrolysis as non-noble metal electrocatalysts for oxygen reductioncitations
- 2018The Evaluation of the Perturbations Induced By Ionic Bombardment on Surfaces: A Challengefor Interfacial Electrochemistry
- 2017Direct Writing on Copper Ion Doped Silica Films by Electrogeneration of Metallic Microstructurescitations
- 2014Ion beam synthesis of embedded III‐As nanocrystals in silicon substratecitations
Places of action
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article
Fine tuning of Nb-incorporated TiO2 thin films by atomic layer deposition and application as efficient electron transport layer in perovskite solar cells
Abstract
<jats:p>Access to finely tuned thin films that can act as electron transport layer (ETL) and adapt to the absorber composition and whole cell fabrication process is key to achieve efficient perovskite-based solar cells. In this study, the growth of mixed niobium-titanium oxide (Nb-TiO2) thin films by atomic layer deposition and its use to extract photogenerated electrons is reported. Films were obtained at 200 °C from titanium (IV) i-propoxide, (t-butylimido)tris(diethylamido)niobium(V), and water by introducing Nb2O5 growth cycle in a TiO2 matrix. Process parameters (order of precursor introduction, cycle ratio) were optimized; the growth mechanism and the effective Nb incorporation were investigated by an in situ quartz crystal microbalance and x-ray photoelectron spectroscopy. The composition, morphology, structural, and optoelectronic properties of the as-deposited films were determined using a variety of characterization techniques. As a result, a fine control of the film properties (between TiO2 and Nb2O5 ones) could be achieved by tuning Nb content. To allow a successful implementation in solar devices, a comprehensive annealing study under several conditions (temperatures, various atmospheres) was conducted leading to an evolution of the optical properties due to a morphological change. Ultimately, the incorporation of these 15 nm-thick films in mesoscopic perovskite solar cells as ETL shows an improvement of the cell performances and of their stability with increasing Nb content, in comparison of both TiO2 and Nb2O5 pure compounds, reaching power conversion efficiency up to 18.3% and a stability above 80% of its nominal value after 138 h under illumination.</jats:p>