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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Laplace, Annabelle
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Publications (7/7 displayed)
- 2024Process for incineration and in can vitrification: glass melt/liquid metal interactions and the multiphasic packagecitations
- 2023Glass formulation approach for mixed technological waste vitrification involving a rheological study of NCAS glasses
- 2023Study of the Crystallization in a Glass-Ceramic Sealcitations
- 2023Study of a glass-ceramic seal : porosity and sealing
- 2020Experimental and numerical investigations of an oxygen single‐bubble shrinkage in a borosilicate glass‐forming liquid doped with cerium oxidecitations
- 2017Hafnium solubility determination in soda-lime aluminosilicate glasscitations
- 2009Potentialities of fluoride-based salts for specific nuclear reprocessing: Overview of the R&D program at CEAcitations
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article
Experimental and numerical investigations of an oxygen single‐bubble shrinkage in a borosilicate glass‐forming liquid doped with cerium oxide
Abstract
The shrinkage of an oxygen single-bubble is investigated in a cerium-doped borosil-icate glass melt at 1150°C. Nine glass samples are synthesized and investigated, utilizing three different amounts of Ce2O3 and three different redox ratios (Ce-(III)/Ce total). Employing in-situ observation, the single-bubble behavior is recorded with a camera. For each glass melt, five experiments are performed with different initial bubble radii. The shrinkage rate (da/dt) depends strongly on the cerium content as well as the redox ratio. Numerical calculations are also conducted to support the understanding of the bubble shrinkage mechanism in the given cases. The model adequately estimates the experimental data for several cases, and an explanation is proposed for the cases, in which it does not. Moreover, we demonstrate, physically and mathematically, the influence of the initial radius of the bubble on the mass transfer between the rising bubble and the melt. We confirm the utilization of the "modified Péclet number", which is a dimensionless number that takes into consideration the influence of multivalent elements on mass transfer. Finally, we master the bubble shrinkage behavior by normalizing the experimental data employing a characteristic time for the mass transfer (&tau).