| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Jensen, Lars Rosgaard
Aalborg University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (37/37 displayed)
- 2024Metal-Organic Framework Glass as a Functional Filler Enables Enhanced Performance of Solid-State Polymer Electrolytes for Lithium Metal Batteriescitations
- 2024Explaining an anomalous pressure dependence of shear modulus in germanate glasses based on Reverse Monte Carlo modelling
- 2024Explaining an anomalous pressure dependence of shear modulus in germanate glasses based on Reverse Monte Carlo modelling
- 2024Alcohols as modifiers in metal−bis(acetamide) hybrid coordination network glasses
- 2024Crystallinity dependence of thermal and mechanical properties of glass-ceramic foamscitations
- 2023Comparing the effects of Ga2O3 and Al2O3 on the structure and mechanical properties of sodium borate glassescitations
- 2023Comparing the effects of Ga2O3 and Al2O3 on the structure and mechanical properties of sodium borate glassescitations
- 2023Correlating structure with mechanical properties in lithium borophosphate glassescitations
- 2022Influence of phase separation microstructure on the mechanical properties of transparent modifier-free glassescitations
- 2022Fracture energy of high-Poisson’s ratio oxide glassescitations
- 2022Resolving the Conflict between Strength and Toughness in Bioactive Silica–Polymer Hybrid Materialscitations
- 2022Irradiation-induced toughening of calcium aluminoborosilicate glassescitations
- 2021Mechanical properties of hydrated cesium-lithium aluminoborate glassescitations
- 2020Heat conduction in oxide glasses: Balancing diffusons and propagons by network rigiditycitations
- 2020Heat conduction in oxide glasses: Balancing diffusons and propagons by network rigiditycitations
- 2020Achieving ultrahigh crack resistance in glass through humid agingcitations
- 2020Competitive effects of free volume, rigidity, and self-adaptivity on indentation response of silicoaluminoborate glassescitations
- 2020Fracture toughness of a metal–organic framework glasscitations
- 2019Breaking the Limit of Micro-Ductility in Oxide Glassescitations
- 2019Mechanical property optimization of a zinc borate glass by lanthanum dopingcitations
- 2019Electrospinning of nonwoven aerogel-polyethene terephthalate composite fiber mats by pneumatic transportcitations
- 2019Electrospinning of nonwoven aerogel-polyethene terephthalate composite fiber mats by pneumatic transportcitations
- 2018Deformation and cracking behavior of La2O3-doped oxide glasses with high Poisson's ratiocitations
- 2018Structural Impact of Nitrogen Incorporation on Properties of Alkali Germanophosphate Glassescitations
- 2018Nano-phase separation and structural ordering in silica-rich mixed network former glassescitations
- 2018Structural stability of NaPON glass upon heating in air and nitrogencitations
- 2017Mutual-stabilization in chemically bonded graphene oxide–TiO2 heterostructures synthesized by a sol–gel approachcitations
- 2017Dispersion and functionalization of single-walled carbon nanotubes (SWCNTS) for nanocomposite applicationscitations
- 2017Monitoring self-sensing damage of multiple carbon fiber composites using piezoresistivitycitations
- 2016Structure and mechanical properties of compressed sodium aluminosilicate glassescitations
- 2016A molecular dynamics study on the interaction between epoxy and functionalized graphene sheetscitations
- 2016Strain sensing in single carbon fiber epoxy composites by simultaneous in-situ Raman and piezoresistance measurementscitations
- 2013Processing and characterization of polyurethane nanocomposite foam reinforced with montmorillonite-carbon nanotube hybridscitations
- 2013Evaluation of the anisotropic mechanical properties of reinforced polyurethane foamscitations
- 2012Synthesis of clay-carbon nanotube hybridscitations
- 2012Synthesis of clay-carbon nanotube hybrids:Growth of carbon nanotubes in different types of iron modified montmorillonitecitations
- 2005Microscopic Mechanism of reinforcement in single-wall carbon nanotube/polypropylene nanocomposite
Places of action
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article
Correlating structure with mechanical properties in lithium borophosphate glasses
Abstract
Connecting structure with mechanical properties is needed for improving the mechanical reliability of oxide glasses. Although the mechanical properties of silicate and borosilicate glasses have been intensively studied, this is not the case for phosphate and borophosphate glasses. To this end, we here study the structure, density, glass transition, hardness, elasticity, and cracking behavior of lithium borophosphate glasses. The glasses are designed with different B/P ratios to access different boron and phosphorus speciation. The introduction of boron in the phosphate network increases the average network rigidity because of the reduction in the fraction of nonbridging oxygens as well as the exchange of phosphate groups with more constrained BO 4 groups. These structural changes result in an increase in density, Vickers hardness, glass transition temperature, and Young's modulus, and a decrease in Poisson's ratio for higher B 2 O 3 content. Furthermore, the increase in network rigidity and atomic packing density results in a lower ability of the glasses to densify upon indentation, resulting in an overall decrease in crack initiation resistance. Finally, we find an increase in the fraction of trigonal boron units in the high-B 2 O 3 glasses, which has a significant effect on atomic packing density and Vickers hardness.