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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ritucci, Ilaria
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2024Development of glass sealants for proton conducting ceramic cells:materials, concepts and challengescitations
- 2022Fracture toughness of reactive bonded Co–Mn and Cu–Mn contact layers after long-term agingcitations
- 2022Torsional behaviour of a glass-ceramic joined alumina coated Crofer 22 APU steelcitations
- 2022Torsional behaviour of a glass-ceramic joined alumina coated Crofer 22 APU steelcitations
- 2022Torsional behaviour of a glass-ceramic joined alumina coated Crofer 22 APU steelcitations
- 2021High toughness well conducting contact layers for solid oxide cell stacks by reactive oxidative bondingcitations
- 2019Improving the interface adherence in solid oxide cell stacks:Glass seals and oxygen electrode contact layers
- 2018A Ba-free sealing glass with a high CTE and excellent interface stability optimized for SOFC/SOEC stack applicationscitations
- 2018A Ba-free sealing glass with a high CTE and excellent interface stability optimized for SOFC/SOEC stack applicationscitations
- 2017A Novel SOFC/SOEC Sealing Glass with a Low SiO2 Content and a High Thermal Expansion Coefficient
- 2017A Novel SOFC/SOEC Sealing Glass with a Low SiO2 Content and a High Thermal Expansion Coefficientcitations
- 2017A Novel SOFC/SOEC Sealing Glass with a Low SiO 2 Content and a High Thermal Expansion Coefficientcitations
Places of action
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article
A Ba-free sealing glass with a high CTE and excellent interface stability optimized for SOFC/SOEC stack applications
Abstract
A new glass-ceramic composition containing Si, Mg, Ca, Na, Al, Zr and Bis presented here as sealant for planar SOFCs/SOECs, with the aim ofjoining the metallic interconnect (Crofer22APU) to the solid oxide cell(YSZ electrolyte or CGO barrier layer). Characteristic temperature,thermo-mechanical properties and compositional variations are reviewedand discussed by thermal analyses and in situ XRD, in order to designand optimize the sealing profile and reduce the residual porosity. Theglass after heat treatment partially devitrifies into augite andnepheline with residual glass phase of around 64.3%; aftercrystallization the glass-ceramic sealant has a CTE of 12.8 x 10<sup>-6</sup> K <sup>−1</sup>and it is compliant with the other materials typically used for stackcomponents.. This work shows that the developed glass-ceramic cansuccessfully join the ceramic cell with the Crofer22APU (pre-oxidizedand alumina coating), proven by tests on small and large-scale samples.No signs of unwanted reactions at the glass-metal and the glass-cellinterface are observed and sufficient gas tightness is achieved.