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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Hosier, Ian L.
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (20/20 displayed)
- 2021Enhanced boron nitride/polyolefin blends for high voltage applicationscitations
- 2019High performance polymer blend systems for HVDC applicationscitations
- 2018Polymer blend systems for HVDC cable applicationscitations
- 2018Enhanced electrical and thermal rating materials for renewable power cable connectionscitations
- 2017The effects of water on the dielectric properties of aluminum based nanocompositescitations
- 2017On the effect of functionalizer chain length and water content in polyethylene/silica nanocomposites: Part II – Charge Transportcitations
- 2017On the effect of functionalizer chain length and water content in polyethylene/silica nanocompositescitations
- 2017The effects of water on the dielectric properties of silicon based nanocompositescitations
- 2015The effects of surface hydroxyl groups in polyethylene-silica nanocomposites
- 2014Dielectric studies of polystyrene-based, high-permittivity composite systemscitations
- 2014Effect of water absorption on dielectric properties of nano-silica/polyethylene compositescitations
- 2014Barium titanate and the dielectric response of polystyrene-based composites
- 2013On the dielectric response of silica-based polyethylene nanocompositescitations
- 2013On Nanosilica Surface Functionalization Using Different Aliphatic Chain Length Silane Coupling Agents
- 2013Absorption Current Behaviour of Polyethylene/Silica Nanocomposites
- 2013Permittivity mismatch and its influence on ramp breakdown performance
- 2010An investigation of the potential of ethylene vinyl acetate/polyethylene blends for use in recyclable high voltage cable insulation systems
- 2004Lamellar morphology of random metallocene propylene copolymers studied by atomic force microscopy
- 2003Formation of the alpha and gamma polymorphs in random metallocene-propylene copolymers. Effect of concentration and type of comonomer
- 2000A study of the morphologies and growth kinetics of three monodisperse n-alkanes: C122H246, C162H326 and C246H494
Places of action
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article
On the effect of functionalizer chain length and water content in polyethylene/silica nanocomposites: Part II – Charge Transport
Abstract
The effects of functionalizer chain length and water content were explored in a series of polyethylene/silica nanocomposites. Silane molecules with differing chain lengths (propyl, octyl and octadecyl) were used to vary the nanoparticle surface chemistry, while vacuum drying and water immersion were used to extract water from or add water to samples previously equilibrated under ambient conditions. Electrical conductivity was found to be highly dependent upon water content, while space charge distributions measured using the pulsed electro-acoustic technique revealed that both the rate of charge injection at the electrode interfaces and the charge mobility within the sample bulk were strongly dependent on absorbed water. Changes to the charge transport dynamics due to the functionalizer chain length were, however, subtle. The removal of surface hydroxyl groups appears to be the primary mechanism by which functionalization influences electrical behavior; this reduces water uptake and, as a consequence, modifies charge transport behavior.