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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Praeger, Matthew
University of Southampton
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2021Laser Induced Backwards Transfer (LIBT) of graphene onto glass
- 2020Microscale deposition of 2D materials via laser induced backwards transfer
- 2020Automated 3D labelling of fibroblasts and endothelial cells in SEM-imaged placenta using deep learningcitations
- 2019Automated 3D labelling of fibroblasts in SEM-imaged placenta using deep learning
- 2017The effects of water on the dielectric properties of aluminum based nanocompositescitations
- 2017On the effect of functionalizer chain length and water content in polyethylene/silica nanocomposites: Part II – Charge Transportcitations
- 2017On the effect of functionalizer chain length and water content in polyethylene/silica nanocompositescitations
- 2017The effects of water on the dielectric properties of silicon based nanocompositescitations
- 2016Supporting data for "The effects of water on the dielectric properties of silicon based nanocomposites"
- 2015The effects of surface hydroxyl groups in polyethylene-silica nanocomposites
- 2014Dielectric studies of polystyrene-based, high-permittivity composite systemscitations
- 2014Effect of water absorption on dielectric properties of nano-silica/polyethylene compositescitations
- 2014A simple theoretical model for the bulk properties of nanocomposite materialscitations
- 2014Barium titanate and the dielectric response of polystyrene-based composites
- 2013A dielectric spectroscopy study of the polystyrene/nanosilica model system
- 2013Nano-Silica Filled Polystyrene: Correlating DC Breakdown Strength and Particle Agglomeration.
- 2013The breakdown strength and localised structure of polystyrene as a function of nanosilica fill-fraction
- 2012Fabrication of nanoscale glass fibers by electrospinningcitations
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article
On the effect of functionalizer chain length and water content in polyethylene/silica nanocomposites: Part II – Charge Transport
Abstract
The effects of functionalizer chain length and water content were explored in a series of polyethylene/silica nanocomposites. Silane molecules with differing chain lengths (propyl, octyl and octadecyl) were used to vary the nanoparticle surface chemistry, while vacuum drying and water immersion were used to extract water from or add water to samples previously equilibrated under ambient conditions. Electrical conductivity was found to be highly dependent upon water content, while space charge distributions measured using the pulsed electro-acoustic technique revealed that both the rate of charge injection at the electrode interfaces and the charge mobility within the sample bulk were strongly dependent on absorbed water. Changes to the charge transport dynamics due to the functionalizer chain length were, however, subtle. The removal of surface hydroxyl groups appears to be the primary mechanism by which functionalization influences electrical behavior; this reduces water uptake and, as a consequence, modifies charge transport behavior.