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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Virtanen, Suvi
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2019Understanding the cross-linking reactions in highly oxidized graphene/epoxy nanocomposite systemscitations
- 2016Dielectric breakdown strength and electrical conductivity of low density polyethylene octylnanosilica composite
- 2015Large-area dielectric breakdown performance of polymer films:Part II: Interdependence of filler content, processing and breakdown performance in polypropylene-silica nanocompositescitations
- 2015Bimodal dielectric nanoparticles and nanocomposites
- 2015Balanced nanocomposite thermosetting materials for HVDC and AC applications
- 2014Structure and dielectric breakdown strength of nano calcium carbonate/polypropylene compositescitations
- 2014Improved dielectric breakdown strength using bimodal functionalized silica nanoparticles
- 2014Dielectric breakdown strength of epoxy bimodal-polymer-brush-grafted core functionalized silica nanocompositescitations
- 2014Influence of low amounts of nanostructured silica and calcium carbonate fillers on the large-area dielectric breakdown performance of bi-axially oriented polypropylenecitations
- 2013Structural studies of dielectric polymer nanocomposites
- 2011Characterization of octamethylsilsesquioxane (CH3)8Si8O12 fillers in polypropene matrix
- 2010Dielectric properties and partial discharge endurance of polypropylene-silica nanocompositecitations
Places of action
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article
Dielectric breakdown strength of epoxy bimodal-polymer-brush-grafted core functionalized silica nanocomposites
Abstract
The central goal of dielectric nanocomposite design is to create a large interfacial area between the matrix polymer and nanofillers and to use it to tailor the properties of the composite. The interface can create sites for trapping electrons leading to increased dielectric breakdown strength (DBS). Nanoparticles with a bimodal population of covalently anchored molecules were created using ligand engineering. Electrically active short molecules (oligothiophene or ferrocene) and matrix compatible long poly(glycidyl methacrylate) (PGMA) chains comprise the bimodal brush. The dielectric breakdown strength was evaluated from recessed samples and dielectric spectroscopy was used to study the dielectric constant and loss as a function of frequency. The dielectric breakdown strength and permittivity increased considerably with only 2 wt% filler loading while the dielectric loss remained comparable to the reference epoxy. ; peerReviewed