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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Barrioz, Vincent
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (26/26 displayed)
- 2023A structural, optical and electrical comparison between physical vapour deposition and slot-die deposition of Al:ZnO (AZO)
- 2022Elimination of the carbon-rich layer in Cu2ZnSn(S, Se)4 absorbers prepared from nanoparticle inkscitations
- 2022Routes to Increase Performance for Antimony Selenide Solar Cells using Inorganic Hole Transport Layerscitations
- 2022Ex-situ Ge-doping of CZTS Nanocrystals and CZTSSe Solar Absorber Filmscitations
- 2022Exploring the Role of Temperature and Hole Transport Layer on the Ribbon Orientation and Efficiency of Sb2Se3 cells Deposited via Thermal Evaporation
- 2022Ex situ Ge-doping of CZTS nanocrystals and CZTSSe solar absorber films.citations
- 2022Recovery mechanisms in aged kesterite solar cellscitations
- 2020Innovative fabrication of low-cost kesterite solar cells for distributed energy applications
- 2019Solution processing route to Na incorporation in CZTSSe nanoparticle ink solar cells on foil substratecitations
- 2018Temperature controlled properties of sub-micron thin SnS filmscitations
- 2018Temperature controlled properties of sub-micron thin SnS filmscitations
- 2018Photovoltaic performance of CdS/CdTe junctions on ZnO nanorod arrayscitations
- 2017Effects of Cd 1-x Zn x S alloy composition and post-deposition air anneal on ultra-thin CdTe solar cells produced by MOCVDcitations
- 2017A combined Na and Cl treatment to promote grain growth in MOCVD grown CdTe thin filmscitations
- 2016Sodium Induced Microstructural Changes in MOCVD-Grown CdTe Thin Films
- 2015MOCVD of SnSx thin films for solar cell application
- 2015Influence of CdCl2 activation treatment on ultra-thin Cd1−xZnxS/CdTe solar cellscitations
- 2014Investigation into ultrathin CdTe solar cell Voc using SCAPS modellingcitations
- 2014Investigation into ultrathin CdTe solar cellVocusing SCAPS modellingcitations
- 2014Cadmium Telluride Solar Cells on Ultrathin Glass for Space Applicationscitations
- 2013Developing Monolithically Integrated CdTe Devices Deposited by AP-MOCVD
- 2013Numerical simulation of the deposition process and the epitaxial growth of cadmium telluride thin film in a MOCVD reactorcitations
- 2011Impedance spectroscopy of thin-film CdTe/CdS solar cells under varied illuminationcitations
- 2010A feasibility study towards ultra-thin PV solar cell devices by MOCDV based on a p-i-n structure incorporating pyrite
- 2009Impedance spectroscopy of thin-film CdTe/CdS solar cells under varied illuminationcitations
- 2008The application of a statistical methodology to investigate deposition parameters in CdTe/CdS solar cells grown by MOCVDcitations
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document
Elimination of the carbon-rich layer in Cu2ZnSn(S, Se)4 absorbers prepared from nanoparticle inks
Abstract
Kesterite Cu2ZnSn(S, Se)4 (CZTSSe) is a promising photovoltaic material attracting significant research interests in recent years. Among the variety of techniques employed for preparation of the absorber thin films, the best results are observed for a hydrazine-based method with efficiency up to 12.6 %. On the other hand, Cu2ZnSnS4 (CZTS) nanoparticle inks annealed in the presence of Se have shown efficiency as high as 9.3 %. Importantly, CZTS nanoparticle inks have the power to be compatible with high volume, high value manufacturing with a variety of substrates including flexible foils, plastics and ultra-thin glass. However, one of the current limitations of the nanoparticle ink technology is the presence of a fine-grain (FG) layer between the CZTSSe large grain (LG) layer and the back contact. The presence of this FG layer is likely to reduce device performance via carrier recombination through traps, interface states and increased grain boundary density. CZTS nanoparticles were synthesized by injection of cold sulphur (25 A^ ∘C) into hot metallic precursors ( (225 A^ ∘C) ). The long carbon chain molecule, oleylamine used in the nanoparticle synthesis step is believed to be the direct reason of the FG layer. Herein, a higher soft-baking temperature of 400 A^ ∘C is studied to evaporate the carbon rich solvent efficiently from the nanoparticle precursor thin films before the selenization process. As a result, the absorber is found to be composed of a single LG CZTSSe layer where the carbon-rich FG layer is eliminated.