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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lai, Barry
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2023Scanning x-ray excited optical luminescence of heterogeneity in halide perovskite alloyscitations
- 2023Synergistic Role of Water and Oxygen Leads to Degradation in Formamidinium-Based Halide Perovskites
- 2023Synergistic Role of Water and Oxygen Leads to Degradation in Formamidinium-Based Halide Perovskitescitations
- 2021Role of Cation Ordering on Device Performance in (Ag,Cu)InSe$_{2}$ Solar Cells with KF Post-Deposition Treatmentcitations
- 2021Synchrotron X-ray metrology of dopant distribution and oxidation state in high pressure CVD grown TM 2+ :ZnSe optical fiberscitations
- 2020Moisture-Induced Crystallographic Reorientations and Effects on Charge Carrier Extraction in Metal Halide Perovskite Solar Cellscitations
- 2018Elucidation of Iron Gettering Mechanisms in Boron-Implanted Silicon Solar Cellscitations
- 2018Moving Beyond p-Type mc-Sicitations
- 2018Solubility and Diffusivitycitations
- 2018Moving Beyond p-Type mc-Si: Quantified Measurements of Iron Content and Lifetime of Iron-Rich Precipitates in n-Type Siliconcitations
- 2017Toward Effective Gettering in Boron-Implanted Silicon Solar Cellscitations
- 2016High-Performance and Traditional Multicrystalline Silicon: Comparing Gettering Responses and Lifetime-Limiting Defectscitations
- 2016Finite- vs. infinite-source emitters in silicon photovoltaicscitations
- 2013Improved iron gettering of contaminated multicrystalline silicon by high temperature phosphorus diffusioncitations
- 2011Influence of defect type on hydrogen passivation efficacy in multicrystalline silicon solar cellscitations
- 2010Impact of defect type on hydrogen passivation effectiveness in multicrystalline silicon solar cellscitations
- 2010The Maia X-ray detector array at the Australian Synchrotron: High definition SXRF trace element imaging
Places of action
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article
Solubility and Diffusivity
Abstract
| openaire: EC/FP7/307315/EU//SOLARX ; Light-and elevated temperature-induced degradation (LeTID) is a detrimental effect observed under operating conditions in p-Type multicrystalline silicon (mc-Si) solar cells. In this contribution, we employ synchrotron-based techniques to study the dissolution of precipitates due to different firing processes at grain boundaries in LeTID-Affected mc-Si. The synchrotron measurements show clear dissolution of collocated metal precipitates during firing. We compare our observations with degradation behavior in the same wafers. The experimental results are complemented with process simulations to provide insight into the change in bulk point defect concentration due to firing. Several studies have proposed that LeTID is caused by metal-rich precipitate dissolution during contact firing, and we find that the solubility and diffusivity are promising screening metrics to identify metals that are compatible with this hypothesis. While slower and less soluble elements (e.g., Fe and Cr) are not compatible according to our simulations, the point defect concentrations of faster and more soluble elements (e.g., Cu and Ni) increase after a high-Temperature firing process, primarily due to emitter segregation rather than precipitate dissolution. These results are a useful complement to lifetime spectroscopy techniques, and can be used to evaluate additional candidates in the search for the root cause of LeTID. ; Peer reviewed