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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rytöluoto, Ilkka
VTT Technical Research Centre of Finland
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (68/68 displayed)
- 2024Screening of suitable random copolymer polypropylene blends for HVDC cable insulationcitations
- 2024Screening of suitable random copolymer polypropylene blends for HVDC cable insulationcitations
- 2024Characterization of Isotactic-Polypropylene-Based Compounds for HVDC Cable Insulationcitations
- 2024Characterization of Isotactic-Polypropylene-Based Compounds for HVDC Cable Insulationcitations
- 2023Molecular Layer Deposition of Polyurea on Silica Nanoparticles and Its Application in Dielectric Nanocompositescitations
- 2023Molecular Layer Deposition of Polyurea on Silica Nanoparticles and Its Application in Dielectric Nanocompositescitations
- 2023Molecular Layer Deposition of Polyurea on Silica Nanoparticles and Its Application in Dielectric Nanocompositescitations
- 2023Molecular Layer Deposition of Polyurea on Silica Nanoparticles and Its Application in Dielectric Nanocompositescitations
- 2022Biaxially oriented silica–polypropylene nanocomposites for HVDC film capacitorscitations
- 2022Biaxially oriented silica–polypropylene nanocomposites for HVDC film capacitors: morphology-dielectric property relationships, and critical evaluation of the current progress and limitationscitations
- 2022Biaxially oriented silica–polypropylene nanocomposites for HVDC film capacitors : morphology-dielectric property relationships, and critical evaluation of the current progress and limitationscitations
- 2022Biaxially oriented silica-polypropylene nanocomposites for HVDC film capacitors: Morphology-dielectric property relationships, and critical evaluation of the current progress and limitationscitations
- 2021Dielectric performance of silica-filled nanocomposites based on miscible (PP/PP-HI) and immiscible (PP/EOC) polymer blendscitations
- 2021Dielectric performance of silica-filled nanocomposites based on miscible (PP/PP-HI) and immiscible (PP/EOC) polymer blendscitations
- 2021PP/PP-HI/silica nanocomposites for HVDC cable insulation : Are silica clusters beneficial for space charge accumulation?citations
- 2021Combining good dispersion with tailored charge trapping in nanodielectrics by hybrid functionalization of silicacitations
- 2021Combining good dispersion with tailored charge trapping in nanodielectrics by hybrid functionalization of silicacitations
- 2021PP/PP-HI/silica nanocomposites for HVDC cable insulation: Are silica clusters beneficial for space charge accumulation?citations
- 2021PP/PP-HI/silica nanocomposites for HVDC cable insulation:Are silica clusters beneficial for space charge accumulation?citations
- 2021Deposition of Ureido and Methacrylate Functionalities onto Silica Nanoparticles and Its Effect on the Properties of Polypropylene-Based Nanodielectricscitations
- 2021Deposition of Ureido and Methacrylate Functionalities onto Silica Nanoparticles and Its Effect on the Properties of Polypropylene-Based Nanodielectricscitations
- 2021Deposition of Ureido and Methacrylate Functionalities onto Silica Nanoparticles and Its Effect on the Properties of Polypropylene-Based Nanodielectricscitations
- 2021PP/PP-HI/silica nanocomposites for HVDC cable insulationcitations
- 2020Silica surface modification with liquid rubbers & functional groups for new polyolefin-based dielectric nano-composites
- 2020Silica surface modification with liquid rubbers & functional groups for new polyolefin-based dielectric nano-composites
- 2020Tribological performance of high density polyethylene (HDPE) composites with low nanofiller loadingcitations
- 2020On the Silica Surface Modification and Its Effect on Charge Trapping and Transport in PP-Based Dielectric Nanocompositescitations
- 2020From Laboratory to Industrial Scale:Comparison of Short- and Long-Term Dielectric Performance of Silica-Polypropylene Capacitor Filmscitations
- 2020Influence of polar and unpolar silica functionalization on the dielectric properties of PP/POE nanocompositescitations
- 2020Influence of polar and unpolar silica functionalization on the dielectric properties of PP/POE nanocompositescitations
- 2020Influence of polar and unpolar silica functionalization on the dielectric properties of PP/POE nanocompositescitations
- 2020Feasibility of Mini-Scale Injection Molding for Resource-Efficient Screening of PP-Based Cable Insulation Nanocompositescitations
- 2020Feasibility of Mini-Scale Injection Molding for Resource-Efficient Screening of PP-Based Cable Insulation Nanocompositescitations
- 2020Feasibility of Mini-Scale Injection Molding for Resource-Efficient Screening of PP-Based Cable Insulation Nanocompositescitations
- 2020Silica Functionalization: How Does it Affect Space Charge Accumulation in Nanodielectrics Under DC?
- 2020Silica Functionalization: How Does it Affect Space Charge Accumulation in Nanodielectrics Under DC?
- 2020From Laboratory to Industrial Scalecitations
- 2020Silica surface-modification for tailoring the charge trapping properties of PP/POE based dielectric nanocomposites for HVDC cable applicationcitations
- 2020From Laboratory to Industrial Scale : Comparison of Short- and Long-Term Dielectric Performance of Silica-Polypropylene Capacitor Filmscitations
- 2019Solution Modified Fumed Silica and Its Effect on Charge Trapping Behavior of PP/POE/Silica Nanodielectricscitations
- 2019Surface Modification of Fumed Silica by Plasma Polymerization of Acetylene for PP/POE Blends Dielectric Nanocompositescitations
- 2019Effect of Silica Modification on Charge Trapping Behavior of PP blend/Silica Nanocompositescitations
- 2019Investigation of nanocomposite polypropylene for DC capacitors:A feasibility studycitations
- 2019Silica-Polypropylene Nanocomposites for Film Capacitorscitations
- 2019Surface Modification of Fumed Silica by Dry Silanization for PP/POE-based Dielectric Nanocompositescitations
- 2019Silica-Polypropylene Nanocomposites for Film Capacitors: Structure–Property Studies and the Role of Biaxial Stretching Conditionscitations
- 2019Surface Modification of Fumed Silica by Dry Silanization for PP-based Dielectric Nanocompositescitations
- 2019Investigation of Nanocomposite Polypropylene for DC Capacitors: A Feasibility Studycitations
- 2019Silica-Polypropylene Nanocomposites for Film Capacitors:Structure–Property Studies and the Role of Biaxial Stretching Conditionscitations
- 2018Compounding, Structure and Dielectric Properties of Silica-BOPP Nanocomposite Filmscitations
- 2018Compounding, Structure and Dielectric Properties of Silica-BOPP Nanocomposite Filmscitations
- 2018Short-Term Dielectric Performance Assessment of BOPP Capacitor Films: A Baseline Studycitations
- 2017The Role of Film Processing in the Large-Area Dielectric Breakdown Performance of Nano-Silica-BOPP Filmscitations
- 2017Large-area approach to evaluate DC electro-thermal ageing behavior of BOPP thin films for capacitor insulation systemscitations
- 2017Nanocomposite Polypropylene For DC Cables And Capacitorscitations
- 2017Nanocomposite Polypropylene For DC Cables And Capacitors:A New European Projectcitations
- 2016Differences in AC and DC large-area breakdown behavior of polymer thin filmscitations
- 2016Large-Area Multi-Breakdown Characterization of Polymer Films: A New Approach for Establishing Structure–Processing–Breakdown Relationships in Capacitor Dielectrics
- 2016Role of microstructure in dielectric properties of thermally sprayed ceramic coatingscitations
- 2016Dielectric breakdown properties of mechanically recycled SiO2-BOPP nanocompositescitations
- 2015DC ramp rate effect on the breakdown response of SiO2-BOPP nanocompositescitations
- 2015Effects of thermal aging on the characteristic breakdown behavior of nano-SiO2-BOPP and BOPP filmscitations
- 2015Large-area dielectric breakdown performance of polymer films:Part II: Interdependence of filler content, processing and breakdown performance in polypropylene-silica nanocompositescitations
- 2015Large-area dielectric breakdown performance of polymer films:Part I: Measurement method evaluation and statistical considerations on area-dependencecitations
- 2015Large-area dielectric breakdown performance of polymer films - Part IIcitations
- 2015Large-area dielectric breakdown performance of polymer films - Part I: Measurement method evaluation and statistical considerations on area-dependencecitations
- 2015The role of film processing in the large-area dielectric breakdown performance of nano-silica-BOPP filmscitations
- 2014Influence of low amounts of nanostructured silica and calcium carbonate fillers on the large-area dielectric breakdown performance of bi-axially oriented polypropylenecitations
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document
Influence of polar and unpolar silica functionalization on the dielectric properties of PP/POE nanocomposites
Abstract
<p>This study focuses on the influence of polar and unpolar surface functionalization of silica on the dielectric performance of PP/POE (polypropylene/poly(ethylene-co-octene)) nanocomposites. The silica fillers were surface-modified with unpoalr trimethylethoxysilane (TMES) or polar 3aminopropyl triethoxysilane (APTES). Fourier-Transform Infrared Spectroscopy and Thermogravimetric analysis were performed and confirmed qualitatively and quantitatively the successful silica-silane modification. Silica/PP/POE nanocomposite films were prepared using a mini-extruder. Scanning Electron Microscope images showed good dispersion of the modified silica in the PP/POE matrix. However, the polar silica cluster size (300 nm) is slightly larger than the one of the unpolar silica (100 nm). Thermally Stimulated Depolarization Current (TSDC) characterization data showed that the polar silica introduced deeper charge traps than the unpolar one, which also showed higher trap density. The apparent conductivity measured during the TSDC poling phase indicated that the polar silica filled nanocomposites featured very fast polarization to reach the saturation state, while the unpolar silica had a rather slow polarization rate. From Pulsed Electroacoustic Analysis it was obvious that the space charge is suppressed by addition of the polar silica, but increased by the presence of the unpolar silica.</p>