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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Giura, Paola
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Publications (3/3 displayed)
- 2021Effect of water incorporation on the ionic conduction properties of the solid electrolyte material RbTiO.(HO)citations
- 2018Ca<sub>2</sub>CuO<sub>2</sub>Cl<sub>2</sub>, a redetermination from single-crystal X-ray diffraction datacitations
- 2017The crystal structure of Rb<sub>2</sub>Ti<sub>2</sub>O<sub>5</sub>citations
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article
Ca<sub>2</sub>CuO<sub>2</sub>Cl<sub>2</sub>, a redetermination from single-crystal X-ray diffraction data
Abstract
<jats:p>The crystal structure of Ca<jats:sub>2</jats:sub>CuO<jats:sub>2</jats:sub>Cl<jats:sub>2</jats:sub>, dicalcium oxidocuprate(II) dichloride, was redetermined on the basis of single-crystal X-ray diffraction data using a laboratory Mo anode. Previous structure determinations based on single-crystal X-ray data [Grande & Müller-Buschbaum (1977). <jats:italic>Z. Anorg. Allg. Chem.</jats:italic><jats:bold>429</jats:bold>, 88–90], powder X-ray diffraction data [Yamada <jats:italic>et al.</jats:italic> (2005). <jats:italic>Phys. Rev. B</jats:italic>, <jats:bold>72</jats:bold>, 224503–1–5] or neutron diffraction data [Argyriou <jats:italic>et al.</jats:italic> (1995). <jats:italic>Phys. Rev. B</jats:italic>, <jats:bold>51</jats:bold>, 8434–8437] were confirmed. The present study allowed the refinement of anisotropic displacement parameters for all crystallographic sites, accompanied with higher accuracy and precision for bond lengths and angles. The layered title compound comprises of [CuO<jats:sub>4</jats:sub>] square-planar and [CaO<jats:sub>4</jats:sub>Cl<jats:sub>4</jats:sub>] square-antiprismatic coordination polyhedra, and is the undoped parent compound of a high-temperature superconducting cuprate.</jats:p>