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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dastuto, Matteo
Institut Néel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2023Light elements insertion induced superconductivity in iron-based intermetallics
- 2023Magnetic and structural properties of the iron silicide superconductor LaFeSiH
- 2019Epsilon iron as a spin-smectic statecitations
- 2018Ca<sub>2</sub>CuO<sub>2</sub>Cl<sub>2</sub>, a redetermination from single-crystal X-ray diffraction datacitations
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article
Ca<sub>2</sub>CuO<sub>2</sub>Cl<sub>2</sub>, a redetermination from single-crystal X-ray diffraction data
Abstract
<jats:p>The crystal structure of Ca<jats:sub>2</jats:sub>CuO<jats:sub>2</jats:sub>Cl<jats:sub>2</jats:sub>, dicalcium oxidocuprate(II) dichloride, was redetermined on the basis of single-crystal X-ray diffraction data using a laboratory Mo anode. Previous structure determinations based on single-crystal X-ray data [Grande & Müller-Buschbaum (1977). <jats:italic>Z. Anorg. Allg. Chem.</jats:italic><jats:bold>429</jats:bold>, 88–90], powder X-ray diffraction data [Yamada <jats:italic>et al.</jats:italic> (2005). <jats:italic>Phys. Rev. B</jats:italic>, <jats:bold>72</jats:bold>, 224503–1–5] or neutron diffraction data [Argyriou <jats:italic>et al.</jats:italic> (1995). <jats:italic>Phys. Rev. B</jats:italic>, <jats:bold>51</jats:bold>, 8434–8437] were confirmed. The present study allowed the refinement of anisotropic displacement parameters for all crystallographic sites, accompanied with higher accuracy and precision for bond lengths and angles. The layered title compound comprises of [CuO<jats:sub>4</jats:sub>] square-planar and [CaO<jats:sub>4</jats:sub>Cl<jats:sub>4</jats:sub>] square-antiprismatic coordination polyhedra, and is the undoped parent compound of a high-temperature superconducting cuprate.</jats:p>