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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Viau, Lydie
Institut UTINAM
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2023Copper(I) iodide coordination polymers with triazole substituted pyridine ligands: photophysical and electrical conductivity propertiescitations
- 2023Copper(I) iodide coordination polymers with triazole substituted pyridine ligands: photophysical and electrical conductivity propertiescitations
- 2023A novel conductometric sensor for acetone detection prepared through electro-polymerization of pyrrole-tailed ionic liquid
- 2022Strengthening adhesion of polycarbazole films on ITO surface by covalent electrografting of monomercitations
- 2021Crystal structure of the two-dimensional coordination polymer poly[di-μ-bromido-bis(μ-tetrahydrothiophene)dicopper(I)]citations
- 2020Drug delivery system obtained by hot-melt processing of zein plasticized by a pharmaceutically active ionic liquidcitations
- 2020Inkjet Printable ZnO/PEDOT:PSS Heterojunction for Thin Flexible Semi-Transparent Optoelectronic Sensorscitations
- 2014Full characterization of polypyrrole thin films electrosynthesized in room temperature ionic liquid, water or acetonitrilecitations
- 2014Single-ion conductor nanocomposite organic–inorganic hybrid membranes for lithium batteriescitations
- 2006Optically tunable nonlinearities in polymers based on photoisomerizable metal-based coordination complexescitations
- 2006Optically tunable nonlinearities in polymers based on photoisomerizable metal-based coordination complexescitations
- 2004All-Optical Orientation of Photoisomerizable Octupolar Zinc(II) Complexes in Polymer Filmscitations
Places of action
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article
Crystal structure of the two-dimensional coordination polymer poly[di-μ-bromido-bis(μ-tetrahydrothiophene)dicopper(I)]
Abstract
The polymeric title compound, [Cu 2 Br 2 (C 4 H 8 S) 2 ] n , CP1 , represents an example of a two-dimensional coordination polymer resulting from reaction of CuBr with tetrahydrothiophene (THT) in MeCN solution. The two-dimensional layers consist of two different types of rhomboid-shaped dinuclear Cu(μ 2 -Br) 2 Cu secondary building units (SBUs); one with a quite loose Cu...Cu separation of 3.3348 (10) Å and a second one with a much closer intermetallic contact of 2.9044 (9) Å. These SBUs are interconnected through bridging THT ligands, in which the S atom acts as a four-electron donor bridging each Cu(μ 2 -Br) 2 Cu unit in a μ 2 -bonding mode. In the crystal, the layers are linked by very weak C—H...·Br hydrogen bonds with H...Br distances of 2.95 Å, thus giving rise to a three-dimensional supramolecular network.