| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Bendeif, El-Eulmi
Soleil Synchrotron
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2023Role and Effect of Meso-Structuring Surfactants on Properties and Formation Mechanism of Microfluidic-Enabled Mesoporous Silica Microspherescitations
- 2023Crystal Structure, Hirhfeld Surface Analysis and IR Analysis of 2-Amino-1,9-Dihydro-6H-Purin-6-One-Selenate-Watercitations
- 2023Synthesis, catalytic activity, magnetic study and anticorrosive activity of mild steel in HCl 1 M medium of (H3dien)[Cu(NO3)(C2O4)2].2H2O. A redetermination at 100 Kcitations
- 2021Synthesis, structural elucidation, spectroscopic, Hirshfeld surface analysis and theoretical simulation of a new adeninium orthoperiodate (1−) bis(hydrate) organic–inorganic hybrid crystalscitations
- 2018Conducting Anilate-Based Mixed-Valence Fe(II)Fe(III) Coordination Polymer: Small-Polaron Hopping Model for Oxalate-Type Fe(II)Fe(III) 2D Networkscitations
- 2018Conducting Anilate-Based Mixed-Valence Fe(II)Fe(III) Coordination Polymer: Small-Polaron Hopping Model for Oxalate-Type Fe(II)Fe(III) 2D Networks
- 2018Broadband Emission in a New Two-Dimensional Cd-Based Hybrid Perovskitecitations
- 2017Control of the white-light emission in the mixed two-dimensional hybrid perovskites (C6H11NH3)2[PbBr4−xIx]citations
- 2017In-house time-resolved photocrystallography on the millisecond timescale using a gated X-ray hybrid pixel area detectorcitations
- 2015Structure determination of molecular nanocomposites by combining pair distribution function analysis and solid-state NMRcitations
- 2015Optical Investigation of Broadband White-Light Emission in Self-Assembled Organic-Inorganic Perovskite (C6H11NH3)(2)PbBr4citations
- 2013Room temperature bistability with wide thermal hysteresis in a spin crossover silica nanocompositecitations
- 2013Room temperature bistability with wide thermal hysteresis in a spin crossover silica nanocompositecitations
- 2013Structural reinvestigation of the photoluminescent complex [NdCl2(H2O)(6)]Clcitations
Places of action
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article
In-house time-resolved photocrystallography on the millisecond timescale using a gated X-ray hybrid pixel area detector
Abstract
With the remarkable progress of accelerator-based X-ray sources in terms of intensity and brightness, the investigation of structural dynamics from time-resolved X-ray diffraction methods is becoming widespread in chemistry, biochemistry and materials science applications. Diffraction patterns can now be measured down to the femtosecond timescale using X-ray free electron lasers or table-top laser plasma X-ray sources. On the other hand, the recent developments in photon counting X-ray area detectors offer new opportunities for time-resolved crystallography. Taking advantage of the fast read-out, the internal stacking of recorded images, and the gating possibilities (electronic shutter) of the XPAD hybrid pixel detector, we implemented a laboratory X-ray diffractometer for time-resolved single-crystal X-ray diffraction after pulsed laser excitation, combined with transient optical absorption measurement. The experimental method and instrumental setup are described in detail, and validated using the photoinduced nitrosyl linkage isomerism of sodium nitroprusside, Na 2 [Fe(CN) 5 NO]Á2H 2 O, as proof of principle. Light-induced Bragg intensity relative variations ÁI(hkl)/I(hkl) of the order of 1%, due to the photoswitching of the NO ligand, could be detected with a 6 ms acquisition window. The capabilities of such a laboratory time-resolved experiment are critically evaluated.