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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Katrusiak, Andrzej
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (30/30 displayed)
- 2024High-pressure observation of elusive iodoplumbic acid in different hydronium-hydrate solid formscitations
- 2024Temperature and volumetric effects on structural and dielectric properties of hybrid perovskitescitations
- 2024Unprecedented Richness of Temperature‐ and Pressure‐Induced Polymorphism in 1D Lead Iodide Perovskitecitations
- 2024Structural insight into piezo-solvatochromism of Reichardt's dyecitations
- 2023Helical model of compression and thermal expansioncitations
- 2023Engineering anomalous elastic properties of coordination polymers and their amorphization by employing flexible linkerscitations
- 2022Pressure-Driven Phase Transition in Two-Dimensional Perovskite MHy2PbBr4citations
- 2022Pressure-Driven Phase Transition in Two-Dimensional Perovskite MHy2PbBr4
- 2021Thermostructural and Elastic Properties of PbTe and Pb0.884Cd0.116Te: A Combined Low-Temperature and High-Pressure X-ray Diffraction Study of Cd-Substitution Effectscitations
- 2021Thermostructural and Elastic Properties of PbTe and Pb 0.884 Cd 0.116 Te: A Combined Low-Temperature and High-Pressure X-ray Diffraction Study of Cd-Substitution Effectscitations
- 2020High-pressure preference for reduced water content in porous zinc aspartate hydrates
- 2019Vitrification and New Phases in the Water:Pyrimidine Binary Eutectic Systemcitations
- 2019Dynamic Resolution of Piezosensitivity in Single Crystals of π-Conjugated Moleculescitations
- 2019Band Gap Engineering in MASnBr3and CsSnBr3 Perovskites: Mechanistic Insights through the Application of Pressurecitations
- 2019Environment-Controlled Postsynthetic Modifications of Iron Formate Frameworkscitations
- 2018Zone-Collapse Amorphization Mimicking the Negative Compressibility of a Porous Compoundcitations
- 2018A giant 2-dimensional dielectric response in a compressed hydrogen-bonded hybrid organic-inorganic saltcitations
- 2018Framework and coordination strain in two isostructural hybrid metal-organic perovskitescitations
- 2017Pressure inverse solubility and polymorphism of an edible γ-cyclodextrin-based metal-organic frameworkcitations
- 2016Mechanism of Pressure-Induced Phase Transitions, Amorphization, and Absorption-Edge Shift in Photovoltaic Methylammonium Lead Iodidecitations
- 2015Compressed Arsenolite As4O6 and Its Helium Clathrate As4O6·2Hecitations
- 2015Cascade of High-Pressure Transitions of Claudetite II and the First Polar Phase of Arsenic(III) Oxidecitations
- 2015Conformational conversion of 4,4′-bipyridinium in a hidden high-pressure phasecitations
- 2014Pressure-induced solvate crystallization of 1,4-Diazabicyclo[2.2.2]octane perchlorate with methanolcitations
- 2014Quasistatic disorder of NH⋯N bonds and elastic-properties relationship in 2-phenylimidazole crystalscitations
- 2008X-ray, FT-IR, ESI MS and PM5 studies of Schiff base of gossypol with allylamine and its complexes with alkali metal cations and perchlorate anioncitations
- 2008Anomalous protonic-glass evolution from ordered phase in NH...N hydrogen-bonded dabcoHBF ferroelectriccitations
- 2006Molecular interactions in crystalline dibromomethane and diiodomethane, and the stabilities of their high-pressure and low-temperature phasescitations
- 2006Disproportionation of pyrazine in NH<sup>+</sup>⋯ hydrogen-bonded complexes: New materials of exceptional dielectric responsecitations
- 2001Microscopic instabilities related to H<inf>3</inf>O<sup>+</sup> dynamics in monoguanidinium dioxonium trinitratecitations
Places of action
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article
Structural insight into piezo-solvatochromism of Reichardt's dye
Abstract
<jats:p>To date, accurate modelling of the solvation process is challenging, often over-simplifying the solvent–solute interactions. The interplay between the molecular arrangement associated with the solvation process and crystal nucleation has been investigated by analysis of the piezo-solvatochromic behaviour of Reichardt's dye, ET(1), in methanol, ethanol and acetone under high pressure. High-pressure single-crystal X-ray diffraction and UV–Vis spectroscopy reveal the impact of solute–solvent interactions on the optical properties of ET(1). The study underscores the intricate relationship between solvent properties, molecular conformation and crystal packing. The connection between liquid and solid phases emphasizes the capabilities of high-pressure methods for expanding the field of crystal engineering. The high-pressure environment allowed the determination of the crystal structures reported here that are built from organic molecules fourfold solvated with ethanol or methanol: ET(1)·4CH<jats:sub>3</jats:sub>OH and ET(1)·4C<jats:sub>2</jats:sub>H<jats:sub>5</jats:sub>OH·H<jats:sub>2</jats:sub>O. The observed piezo-solvatochromic effects highlight the potential of ET(1) in nonlinear optoelectronics and expand the application of solvatochromic chemical indicators to pressure sensors.</jats:p>