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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Kriele, Armin
Helmholtz-Zentrum Hereon
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Topics
Publications (11/11 displayed)
- 2024Heterogeneity of Lithium Distribution in the Graphite Anode of 21700-Type Cylindrical Li-Ion Cells during Degradationcitations
- 2024Thermal Structural Behavior of ElectrochemicallyLithiated Graphite (LixC6) Anodes in Li‐ion Batteriescitations
- 2021Morphology–Ionic Conductivity Relationship in Polymer–Titania Hybrid Electrolytes for Lithium-Ion Batteriescitations
- 2020Surface distortion of Fe dot-decorated TiO2 nanotubular templates using time-of-flight grazing incidence small angle scatteringcitations
- 2018Conductivity and Morphology Correlations of Ionic-Liquid/Lithium-Salt/Block Copolymer Nanostructured Hybrid Electrolytescitations
- 2018In Situ Characterization at Elevated Temperatures of a New Ni-Based Superalloy VDM-780 Premiumcitations
- 2016Stability of TaC precipitates in a Co–Re-based alloy being developed for ultra-high-temperature applicationscitations
- 2016Microstructure and Residual Stress in Rotary Friction Welded Dissimilar Metals of AA7020 Aluminium Alloy with 316L Steelcitations
- 2010Anisotropic etching of diamond by molten Ni particlescitations
- 2009Nickel doping of nitrogen enriched CVD‐diamond for the production of single photon emitterscitations
- 2002Enhancing the resolution of scanning near-field optical microscopy by a metal tip grown on an aperture probecitations
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article
Stability of TaC precipitates in a Co–Re-based alloy being developed for ultra-high-temperature applications
Abstract
Co–Re alloys are being developed for ultra-high-temperature applications to supplement Ni-based superalloys in future gas turbines. The main goal of the alloy development is to increase the maximum service temperature of the alloy beyond 1473 K, i.e. at least 100 K more than the present single-crystal Ni-based superalloy turbine blades. Co–Re alloys are strengthened by carbide phases, particularly the monocarbide of Ta. The binary TaC phase is stable at very high temperatures, much greater than the melting temperature of superalloys and Co–Re alloys. However, its stability within the Co–Re–Cr system has never been studied systematically. In this study an alloy with the composition Co–17Re–23Cr–1.2Ta–2.6C was investigated using complementary methods of small-angle neutron scattering (SANS), scanning electron microscopy, X-ray diffraction and neutron diffraction. Samples heat treated externally and samples heated in situ during diffraction experiments exhibited stable TaC precipitates at temperatures up to 1573 K. The size and volume fraction of fine TaC precipitates (up to 100 nm) were characterized at high temperatures with in situ SANS measurements. Moreover, SANS was used to monitor precipitate formation during cooling from high temperatures. When the alloy is heated the matrix undergoes an allotropic phase transformation from the ∊ phase (hexagonal close-packed) to the γ phase (face-centred cubic), and the influence on the strengthening TaC precipitates was also studied with in situ SANS. The results show that the TaC phase is stable and at these high temperatures the precipitates coarsen but still remain. This makes the TaC precipitates attractive and the Co–Re alloys a promising candidate for high-temperature application.