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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Gilles, Ralph
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Lithium Redistribution Mechanism within Silicon-Graphite Electrodes: Multi-Method Approach and Method Validationcitations
- 2024Observation of preferential sputtering of Si/graphite anodes from Li-ion cells by GD-OES and its validation by neutron depth profilingcitations
- 2024Dendritic Copper Current Collectors as a Capacity Boosting Material for Polymer-Templated Si/Ge/C Anodes in Li-Ion Batteriescitations
- 2023Investigation of the Hot Deformation Behavior in VDM® Alloy 780 by In Situ High-Energy X-Ray Diffractioncitations
- 2023Combined X-ray and Neutron Powder Diffraction Study on B-Site Cation Ordering in Complex Perovskite La2(Al1/2MgTa1/2)O6
- 2022Cracking during High-Temperature Deformation of a High-Strength Polycrystalline CoNi-Base Superalloy
- 2021TaC Precipitation Kinetics During Cooling of Co−Re‐Based Alloyscitations
- 2021Morphology–Ionic Conductivity Relationship in Polymer–Titania Hybrid Electrolytes for Lithium-Ion Batteriescitations
- 2021Deformation Mechanisms in Ni-Based Superalloys at Room and Elevated Temperatures Studied by In Situ Neutron Diffraction and Electron Microscopycitations
- 2020HRTEM analysis of the high-temperature phases of the newly developed high-temperature Ni-base superalloy VDM 780 Premiumcitations
- 2018Creep deformation of Co-Re-Ta-C alloys with varying C content – investigated in-situ by simultaneous synchrotron radiation diffractioncitations
- 2018Conductivity and Morphology Correlations of Ionic-Liquid/Lithium-Salt/Block Copolymer Nanostructured Hybrid Electrolytescitations
- 2016Stability of TaC precipitates in a Co–Re-based alloy being developed for ultra-high-temperature applicationscitations
- 2015GISAXS and TOF-GISANS studies on surface and depth morphology of self-organized TiO 2 nanotube arrays: model anode material in Li-ion batteriescitations
- 2014Effects of size reduction on the structure and magnetic properties of core-shell Ni 3 Si/silica nanoparticles prepared by electrochemical synthesiscitations
- 2013Application of In Situ Neutron and X-Ray Measurements at High Temperatures in the Development of Co-Re-Based Alloys for Gas Turbinescitations
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article
Stability of TaC precipitates in a Co–Re-based alloy being developed for ultra-high-temperature applications
Abstract
Co–Re alloys are being developed for ultra-high-temperature applications to supplement Ni-based superalloys in future gas turbines. The main goal of the alloy development is to increase the maximum service temperature of the alloy beyond 1473 K, i.e. at least 100 K more than the present single-crystal Ni-based superalloy turbine blades. Co–Re alloys are strengthened by carbide phases, particularly the monocarbide of Ta. The binary TaC phase is stable at very high temperatures, much greater than the melting temperature of superalloys and Co–Re alloys. However, its stability within the Co–Re–Cr system has never been studied systematically. In this study an alloy with the composition Co–17Re–23Cr–1.2Ta–2.6C was investigated using complementary methods of small-angle neutron scattering (SANS), scanning electron microscopy, X-ray diffraction and neutron diffraction. Samples heat treated externally and samples heated in situ during diffraction experiments exhibited stable TaC precipitates at temperatures up to 1573 K. The size and volume fraction of fine TaC precipitates (up to 100 nm) were characterized at high temperatures with in situ SANS measurements. Moreover, SANS was used to monitor precipitate formation during cooling from high temperatures. When the alloy is heated the matrix undergoes an allotropic phase transformation from the ∊ phase (hexagonal close-packed) to the γ phase (face-centred cubic), and the influence on the strengthening TaC precipitates was also studied with in situ SANS. The results show that the TaC phase is stable and at these high temperatures the precipitates coarsen but still remain. This makes the TaC precipitates attractive and the Co–Re alloys a promising candidate for high-temperature application.