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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Fiebig, Manfred
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Topics
Publications (13/13 displayed)
- 2024Combined Electrostatic and Strain Engineering of BiFeO<sub>3</sub> Thin Films at the Morphotropic Phase Boundarycitations
- 2024Combined electrostatic and strain engineering of BiFeO 3 thin films at the morphotropic phase boundarycitations
- 2020Robust in-plane ferroelectricity in ultrathin epitaxial aurivillius filmscitations
- 2019High-speed domain wall racetracks in a magnetic insulatorcitations
- 2019Ultrathin regime growth of atomically flat multiferroic gallium ferrite films with perpendicular magnetic anisotropycitations
- 2019Current-induced switching of YIG/Pt bilayers with in-plane magnetization due to Oersted fieldscitations
- 2017Microstructure and ferroelectricity of BaTiO 3 thin films on Si for integrated photonicscitations
- 2016Optimization of electronic domain-wall properties by aliovalent cation substitutioncitations
- 2015Magnetoresistance of heavy and light metal/ferromagnet bilayerscitations
- 2015Low-threshold amplified spontaneous emission and lasing from colloidal nanocrystals of caesium lead halide perovskitescitations
- 2015Low-threshold amplified spontaneous emission and lasing from colloidal nanocrystals of caesium lead halide perovskites (vol 6, 8056, 2015)citations
- 2014Structural invariance upon antiferromagnetic ordering in geometrically frustrated swedenborgite, CaBaCo2Fe2O7citations
- 2011Optical second- and third-harmonic generation on the ferromagnetic semiconductor europium oxidecitations
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article
Structural invariance upon antiferromagnetic ordering in geometrically frustrated swedenborgite, CaBaCo2Fe2O7
Abstract
<jats:p>Centimetre-sized single crystals of high-quality CaBaCo<jats:sub>2</jats:sub>Fe<jats:sub>2</jats:sub>O<jats:sub>7</jats:sub>were synthesized by the optical floating zone technique. The metal-to-metal stoichiometry and oxygen content were confirmed by spectroscopy and thermal reduction experiments. The hexagonal symmetry<jats:italic>P</jats:italic>6<jats:sub>3</jats:sub><jats:italic>mc</jats:italic>(No. 186) well describes the powder X-ray and neutron diffraction as well as single-crystal neutron diffraction at all measured temperatures. This symmetry is also consistent with optical second harmonic generation data obtained between 10 and 295 K. However, a satisfactory structure description from single-crystal neutron diffraction data needs an oxygen split position. Specific heat, magnetic susceptibility and powder neutron diffraction data indicate a magnetic phase transition at<jats:italic>T</jats:italic><jats:sub>N</jats:sub>= 159 K to an antiferromagnetic ground state, but with a persisting hexagonal symmetry and intrinsic geometric frustration.</jats:p>