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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Czarnecki, Piotr
Adam Mickiewicz University in Poznań
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2022Above-room-temperature ferroelectricity and piezoelectric activity of dimethylglycinium-dimethylglycine chloridecitations
- 2012New ferroelectric: Bis-thiourea pyridinium bromide inclusion compoundcitations
- 2012Structures and phase transitions in a new ferroelectric-pyridinium chlorochromate-studied by X-ray diffraction, DSC and dielectric methodscitations
- 2010The neutron diffraction study, calorimetry and spontaneous polarization of pyridinium perrhenate at 350, 300 and 100Kcitations
- 2009Discovery of an intermediate phase in bis-thiourea pyridinium chloride inclusion compound.citations
- 2009Discovery of an intermediate phase in bis-thiourea pyridinium chloride inclusion compoundcitations
- 2008Redetermination of the structure and dielectric properties of bis(thiourea) pyridinium iodide - A new ferroelectric inclusion compoundcitations
- 2007Phase transitions in ferroelectric pyridinium periodide under high pressurecitations
- 2006Structure, phase transitions and dielectric properties of a new inclusion compound of bis-thiourea pyridinium nitrate saltcitations
- 2006Dielectric response of the relaxor ferroelectric Pb(Mg<inf>1/3</inf>Nb <inf>2/3</inf>)O<inf>3</inf> in the nonergodic state after a DC electric field is turned off
- 2005Decoupling of the order-disorder and displacive contributions to the phase transition in NH<inf>4</inf>H(ClH<inf>2</inf>CCOO)<inf>2</inf>citations
- 2005Compositional and pressure effects on the phase transition in ferroelectric NH<inf>4</inf>H(ClH<inf>2</inf>CCOO)<inf>2</inf>
- 2003Effect of hydrostatic pressure on the dielectric response of Pb(Mg 1/3Nb2/3)O3 relaxorcitations
- 2003The neutron diffraction study of pyridinium periodate at 352, 300 and 100 Kcitations
- 20012-5 pyrochlore relaxor ferroelectric Cd<inf>2</inf>Nb<inf>2</inf>O<inf>7</inf> and its Fe<sup>2+</sup>/Fe<sup>3+</sup> modificationscitations
- 2001Structure and dynamics of ferroelectric pyridinium periodatecitations
- 2000High pressure study of cation dynamics in pyridinium Perchloratecitations
- 2000Structure and dielectric properties of ferroelectric pyridinium perrhenate crystalscitations
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article
Structures and phase transitions in a new ferroelectric-pyridinium chlorochromate-studied by X-ray diffraction, DSC and dielectric methods
Abstract
<p>Pyridinium chlorochromate, [C <sub>5</sub>H <sub>5</sub>NH] <sup>+</sup>[ClCrO <sub>3</sub>] <sup>-</sup> (hereafter referred to as PyClCrO <sub>3</sub>), was studied by X-ray diffraction, differential scanning calorimetry (DSC) and dielectric methods. Studies reveal three reversible phase transitions at 346, 316 and 170 K with the following phase sequence: (I) →R3m (II) →Cm (III) →Cc (IV), c′ = 2c. PyClCrO <sub>3</sub> is the first pyridinium salt in which all four phases have been successfully characterized by a single-crystal X-ray diffraction method. Structural results together with dielectric and calorimetric studies allow the classification of the two intermediate phases (II) and (III) as ferroelectric with the Curie point at 346 K, and the lowest phase (IV) as most probably ferroelectric. The ferroelectric hysteresis loop was observed only in phase (III). The high ionic conductivity hindered its observation in phase (II). © 2012 International Union of Crystallography Printed in Singapore-all rights reserved.</p>