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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bell, Anthony Martin Thomas
Sheffield Hallam University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2024Atom Probe Tomography Investigation of Clustering in Model P2O5-Doped Borosilicate Glasses for Nuclear Waste Vitrification
- 2023Dynamic high‐temperature crystallization and processing properties of industrial soda–lime–silica glassescitations
- 2021Thermostructural and Elastic Properties of PbTe and Pb0.884Cd0.116Te: A Combined Low-Temperature and High-Pressure X-ray Diffraction Study of Cd-Substitution Effectscitations
- 2021Crystal structures and X-ray powder diffraction data for Cs2NiSi5O12, RbGaSi2O6, and CsGaSi2O6 synthetic leucite analogues
- 2020X-ray Fluorescence Analysis of Feldspars and Silicate Glass: Effects of Melting Time on Fused Bead Consistency and Volatilisationcitations
- 2016Rietveld refinement of the crystal structures of Rb2XSi5O12(X= Ni, Mn)citations
- 2013Synchrotron X-ray powder diffraction study on synthetic Sr-Fresnoitecitations
- 2012High-temperature synchrotron X-ray powder diffraction study of Cs2XSi5O12(X = Cd, Cu, Zn) leucitescitations
- 2010Revision of the structure of Cs2CuSi5O12 leucite as orthorhombic Pbcacitations
- 2010Structural evolution of aqueous mercury sulphide precipitates: energy-dispersive X-ray diffraction studiescitations
- 2009Crystal structures and cation ordering in Cs2MgSi5O12, Rb2MgSi5O12 and Cs2ZnSi5O12 leucitescitations
- 2009Synchrotron X-ray absorption spectroscopy and X-ray powder diffraction studies of the structure of johnbaumite [Ca10(AsO4)6(OH,F)2] and synthetic Pb-, Sr- and Ba-arsenate apatites and some comments on the crystal chemistry of the apatite structure type in generalcitations
- 2008Polymorphism in cyclohexanolcitations
- 2001Chemically induced magnetism and magnetoresistance in La(0.8)Sr(1.2)Mn(0.6)Rh(0.4)O(4).
Places of action
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article
Revision of the structure of Cs2CuSi5O12 leucite as orthorhombic Pbca
Abstract
<jats:p>The crystal structure of a hydrothermally synthesized leucite analogue Cs<jats:sub>2</jats:sub>CuSi<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub> has been determined and refined using the Rietveld method from high-resolution synchrotron X-ray and neutron powder diffraction data. This structure is based on the topology and cation-ordering scheme of the <jats:italic>Pbca</jats:italic> leucite structure of Cs<jats:sub>2</jats:sub>CdSi<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub>, and exhibits five ordered Si sites and one ordered Cu tetrahedrally coordinated (<jats:italic>T</jats:italic>) site. This structure for Cs<jats:sub>2</jats:sub>CuSi<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub> is topologically identical to other known leucite structures and is different from that originally proposed by Heinrich & Baerlocher [(1991), <jats:italic>Acta Cryst.</jats:italic> C<jats:bold>47</jats:bold>, 237–241] in the tetragonal space group P4_12_12. The crystal structure of a dry-synthesized leucite analogue Cs<jats:sub>2</jats:sub>CuSi<jats:sub>5</jats:sub>O<jats:sub>12</jats:sub> has also been refined; this has the Ia 3d cubic pollucite structure with disordered <jats:italic>T</jats:italic> sites.</jats:p>