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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Figueira, Cláudia A.
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Topics
Publications (3/3 displayed)
- 2018New phenyl-nickel complexes of bulky 2-iminopyrrolyl chelatescitations
- 2015Exploring the influence of steric hindrance and electronic nature of substituents in the supramolecular arrangements of 5-(substituted phenyl)-2-formylpyrrolescitations
- 2009Trans-Chlorido(phen-yl)bis-(triphenyl-phosphine)nickel(II) and its 1:1 cocrystal with chloridobis(triphenyl-phosphine)nickel(I)citations
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article
Trans-Chlorido(phen-yl)bis-(triphenyl-phosphine)nickel(II) and its 1:1 cocrystal with chloridobis(triphenyl-phosphine)nickel(I)
Abstract
<p>Two conformational polymorphs of trans-chlorido(phenyl)bis-(triphenyl- phosphine)nickel(II), [Ni(C<sub>6</sub>H<sub>5</sub>)Cl(Cl8H15P)<sub>2</sub>], (1), viz. orange needle-shaped crystals (form I) and brown prism-shaped crystals (form II), were obtained under different crystallization conditions from a mixture of toluene and n-hexane, and characterized by single-crystal X-ray diffraction at low temperature. These two forms were compared with that published previously [Zeller, Herdtweck & Strassner (2003). Eur. J. Inorg. Chem. pp. 1802-1806], characterized at room temperature. Additionally, blue-green prisms of a 1:1 co-crystal of complex (1) with chloridobis(triphenyl- phos-phine)-nickel(I), (2), viz. trans-chlorido(phenyl)bis(tri-phenyl-phos- phine)nickel(II)-chloridobis(tri-phenyl-phos-phine)nickel(I) (1/1), [Ni(C <sub>6</sub>H<sub>5</sub>)Cl(Cl8H15P)<sub>2</sub>]·[NiCl(Cl8H15P) <sub>2</sub>], (3), were obtained concomitantly with form I. In forms I and II, as well as in the cocrystal, the overall crystal packings are determined by an energetic inter-play between intra-molecular torsions and weak inter-molecular C - H⋯π and C - H⋯Cl inter-actions.</p>