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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Ten Brink, Gert H.
University of Groningen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (32/32 displayed)
- 2024Bridging the gap between high-entropy alloys and metallic glasses:Control over disorder and mechanical properties of coatings
- 2022Taking a closer look - how the microstructure of Dion-Jacobson perovskites governs their photophysics.
- 2022Nanostructure and thermal power of highly-textured and single-crystal-like Bi2Te3 thin filmscitations
- 2022Nanostructure and thermal power of highly-textured and single-crystal-like Bi2Te3 thin filmscitations
- 2022Taking a closer look - how the microstructure of Dion-Jacobson perovskites governs their photophysics
- 2022Taking a closer look - how the microstructure of Dion-Jacobson perovskites governs their photophysicscitations
- 2021Tunable wettability of polymer films by partial engulfment of nanoparticlescitations
- 2021Tunable wettability of polymer films by partial engulfment of nanoparticlescitations
- 2020Microstructure, precipitate and property evolution in cold-rolled Ti-V high strength low alloy steelcitations
- 2020Microstructure, precipitate and property evolution in cold-rolled Ti-V high strength low alloy steelcitations
- 2020Microstructure, precipitate and property evolution in cold-rolled Ti-V high strength low alloy steelcitations
- 2020Unraveling the Microstructure of Layered Metal Halide Perovskite Filmscitations
- 2020Unraveling the Microstructure of Layered Metal Halide Perovskite Filmscitations
- 2020Stable cesium formamidinium lead halide perovskites: a comparison of photophysics and phase purity in thin films and single crystalscitations
- 2019Stable Cesium Formamidinium Lead Halide Perovskitescitations
- 2019Mechanism of surface passivation of methylammonium lead tribromide single crystals by benzylaminecitations
- 2019Mechanism of surface passivation of methylammonium lead tribromide single crystals by benzylaminecitations
- 2019Enhancing the crystallinity and perfecting the orientation of formamidinium tin iodide for highly efficient Sn-based perovskite solar cellscitations
- 2019The Impact of Stoichiometry on the Photophysical Properties of Ruddlesden-Popper Perovskitescitations
- 2019Stable Cesium Formamidinium Lead Halide Perovskites:A Comparison of Photophysics and Phase Purity in Thin Films and Single Crystalscitations
- 2019Investigation of the Nanoscale Morphology in Industrially Relevant Clearcoats of Waterborne Polymer Colloids by Means of Variable-Angle-Grazing Incidence Small-Angle X-ray Scatteringcitations
- 2018Micropatterned 2D Hybrid Perovskite Thin Films with Enhanced Photoluminescence Lifetimescitations
- 2018Combining Ultrafast Calorimetry and Electron Microscopycitations
- 2018Combining Ultrafast Calorimetry and Electron Microscopy:Reversible Phase Transformations in SeTeAs Alloyscitations
- 2018Shape and structural motifs control of MgTi bimetallic nanoparticles using hydrogen and methane as trace impuritiescitations
- 2017N-Type Organic Thermoelectricscitations
- 2016N-type polymers as electron extraction layers in hybrid perovskite solar cells with improved ambient stabilitycitations
- 2014Synthesis and exceptional thermal stability of Mg-based bimetallic nanoparticles during hydrogenationcitations
- 2013Tuning structural motifs and alloying of bulk immiscible Mo-Cu bimetallic nanoparticles by gas-phase synthesiscitations
- 2010Microstructural features of intergranular brittle fracture and cold cracking in high strength aluminum alloyscitations
- 2006The growth-induced microstructural origin of the optical black state of Mg2NiHx thin filmscitations
- 2006Optical, structural, and electrical properties of Mg2NiH4 thin films in situ grown by activated reactive evaporationcitations
Places of action
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article
Tunable wettability of polymer films by partial engulfment of nanoparticles
Abstract
<p>A series of poly(methyl methacrylate) (PMMA) surfaces decorated by Cu nanoparticles (NP) with gradually varied morphology were prepared by high-pressure CO2 treatment at various time spans. Combining the characterizations of transmission electron microscopy (TEM) and atomic force microscopy (AFM), an accurate three-dimensional view of the morphology of the surfaces was presented. Subsequently, the wettability of the surfaces decreases near linearly with the increase of the apparent height of the decorating NPs in both static (static contact angle) and dynamic (contact angle hysteresis) aspects. The observed tendency contradicts to the Wenzel or Cassie-Baxter model and is explained by the contribution of nanomeniscus formed between the decorating NP and the flat substrate. The capillary pressure from this meniscus is negative and results in the increase of the contact angle with the apparent height (H-N) of the Cu NPs decorating the PMMA surface. In addition, the effect of the coverage (C-N) by NPs on the wettability can be explained on the same basis. Our experiment demonstrates the important influence of the nanomeniscus on the wettability, which is usually not taken into account. The results in this work provide a comprehensive understanding of how nanostructure affects the wettability of the decorated surfaces and shed light on how to obtain certain wettability through nanostructuring of the surface morphology.</p>