693.932 PEOPLE
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| Naji, M. |
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| Motta, Antonella |
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| Azevedo, Nuno Monteiro |
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| Rignanese, Gian-Marco |
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Schreuders, Herman
Delft University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024Structural and Optical Properties of Thin Film β-Ta upon Exposure to Hydrogen to Asses Its Applicability as Hydrogen Sensing Materialcitations
- 2024Towards hydrogen fueled aircraft
- 2024Advancing Hydrogen Sensing for Sustainable Aviationcitations
- 2023In-situ S/TEM Visualization of Metal-to-Metal Hydride Phase Transformation of Magnesium Thin Films
- 2023Tuning the Properties of Thin-Film TaRu for Hydrogen-Sensing Applicationscitations
- 2020Metallurgical Synthesis of Mg2FexSi1- x Hydridecitations
- 2019Metal-polymer hybrid nanomaterials for plasmonic ultrafast hydrogen detectioncitations
- 2019Metal-polymer hybrid nanomaterials for plasmonic ultrafast hydrogen detectioncitations
- 2019Effect of the addition of zirconium on the photochromic properties of yttrium oxy-hydridecitations
- 2018Elastic versus Alloying Effects in Mg-Based Hydride Filmscitations
- 2017Enhancement of Destabilization and Reactivity of Mg Hydride Embedded in Immiscible Ti Matrix by Addition of Crcitations
- 2017Photochromism of rare-earth metal-oxy-hydridescitations
- 2015Destabilization of Mg Hydride by Self-Organized Nanoclusters in the Immiscible Mg-Ti System
- 2012Optical hydrogen sensors based on metal-hydridescitations
- 2012Combined XPS and first principle study of metastable Mg-Ti thin filmscitations
- 2006Structural and optical properties of MgxAl1-xH y gradient thin filmscitations
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article
Elastic versus Alloying Effects in Mg-Based Hydride Films
Abstract
Magnesium thin films covered with a layer of Pd absorb hydrogen at much higher pressures than bulk Mg. Such an effect was originally explained as a consequence of elastic clamping on Mg by the capping Pd layer. An alternative interpretation later suggested that the pressure increase could originate from simple alloying between Mg and Pd. Here we resolve this controversy by measuring the hydrogenation and dehydrogenation isotherms of Mg-Pd thin film alloys over a wide range of compositions. Our results disentangle the effects of elastic clamping and alloying and highlight the role of plastic deformations.