| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Stadtmüller, Benjamin
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (22/22 displayed)
- 2024Coherent and incoherent magnons induced by strong ultrafast demagnetization in thin permalloy filmscitations
- 2024Revealing hidden spin polarization in centrosymmetric van der Waals materials on ultrafast timescalescitations
- 2024Enhancing the dipole ring of hexagonal boron nitride nanomesh by surface alloyingcitations
- 2023Effect of iron thicknesses on spin transport in a Fe/Au bilayer system
- 2022Atomic and mesoscopic structure of Dy-based surface alloys on noble metalscitations
- 2021Energy and momentum distribution of surface plasmon-induced hot carriers isolated via spatiotemporal separationcitations
- 2020Vertical bonding distances and interfacial band structure of PTCDA on a Sn-Ag surface alloycitations
- 2020Modification of the charge and magnetic order of a low dimensional ferromagnet by molecule-surface bonding
- 2019Exchange Splitting of a Hybrid Surface State and Ferromagnetic Order in a 2D Surface Alloy
- 2018Adsorption-induced pyramidal distortion of the trimetallic nitride core inside the endohedral fullerene Sc3N@C80 on the Ag(111) surfacecitations
- 2018Adsorption-induced pyramidal distortion of the trimetallic nitride core inside the endohedral fullerene Sc 3 N @ C 80 on the Ag(111) surfacecitations
- 2017Fully Atomistic Understanding of the Electronic and Optical Properties of a Prototypical Doped Charge-Transfer Interfacecitations
- 2017Fully atomistic understanding of the electronic and optical properties of a prototypical doped charge-transfer interfacecitations
- 2016Epitaxial growth of thermally stable cobalt films on Au(111)citations
- 2016Adsorption heights and bonding strength of organic molecules on a Pb-Ag surface alloycitations
- 2015Topological states on the gold surfacecitations
- 2015Tailoring metal–organic hybrid interfaces: heteromolecular structures with varying stoichiometry on Ag(111)citations
- 2015Tailoring metal–organic hybrid interfaces: heteromolecular structures with varying stoichiometry on Ag(111)citations
- 2014Molecular exchange in a heteromolecular PTCDA/CuPc bilayer film on Ag(111)citations
- 2014Electrostatic interaction and commensurate registry at the heteromolecular F16CuPc–CuPc interfacecitations
- 2010Structural influence on the Rashba-type spin splitting in surface alloyscitations
- 2010Submonolayer growth of copper-phthalocyanine on Ag(111)citations
Places of action
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article
Adsorption-induced pyramidal distortion of the trimetallic nitride core inside the endohedral fullerene Sc3N@C80 on the Ag(111) surface
Abstract
Our ability to understand and tailor metal-organic interfaces is mandatory to functionalize organic complexes for next generation electronic and spintronic devices. For magnetic data storage applications, metal-carrying organic molecules, the so-called single molecular magnets (SMM) are of particular interest as they yield the possibility to store information on the molecular scale. In this work, we focus on the adsorption properties of the prototypical SMM Sc3N@C80 grown in a monolayer film on the Ag(111) substrate. We provide clear evidence of a pyramidal distortion of the otherwise planar Sc3N core inside the carbon cage upon the adsorption on the Ag(111) surface. This adsorption-induced structural change of the Sc3N@C80 molecule can be correlated to a charge transfer from the substrate into the lowest unoccupied molecular orbital of Sc3N@C80, which significantly alters the charge density of the fullerene core. Our comprehensive characterization of the Sc3N@C80-Ag(111) interface hence reveals an indirect coupling mechanism between the Sc3N core of the fullerene molecule and the noble metal surface mediated via an interfacial charge transfer. Our work shows that such an indirect coupling between the encapsulated metal centers of SMM and metal surfaces can strongly affect the geometric structure of the metallic centers and thereby potentially also alters the magnetic properties of SMMs on surfaces.