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Marín, José Manuel Román
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Publications (6/6 displayed)
- 2013A control scheme for filament stretching rheometers with application to polymer meltscitations
- 2013Creep measurements confirm steady flow after stress maximum in extension of branched polymer meltscitations
- 2012Mechanism of spontaneous hole formation in thin polymeric filmscitations
- 2012Planar elongation of soft elastomeric networks
- 2012Bimodal Networks as Candidates for Electroactive Polymers
- 2011Filament Stretching Rheometry
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article
Mechanism of spontaneous hole formation in thin polymeric films
Abstract
We show computationally that (molten) thin polymeric film containing nonequilibrium configurations originating from a solvent evaporation may develop holes spontaneously in the molten state, and that they appear delayed. Polymers above the glass transition temperature are liquids where the flow depends solely on the nonequilibrium configurations of the molecules.