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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sartbaeva, Asel
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2019Defective hierarchical porous copper-based metal-organic frameworks synthesised via facile acid etching strategycitations
- 2019Defective hierarchical porous copper-based metal-organic frameworks synthesised via facile acid etching strategycitations
- 2019Formation and characterisation of ZnS nanoclusters in the pore channels of modernite zeolite
- 2017Defining the flexibility window in ordered aluminosilicate zeolitescitations
- 2017Local and Average Structural Changes in Zeolite A upon Ion Exchangecitations
- 2015GASP: software for geometric simulations of flexibility in polyhedral and molecular framework structurescitations
- 2011Flexibility windows and phase transitions of ordered and disordered ANA framework zeolitescitations
- 2009Compression behaviour and flexibility window of the analcime like feldspathoids: experimental and theoretical findingscitations
- 2008Flexibility window controls pressure-induced phase transition in analcimecitations
- 2008Search for a structural response to the intermediate phase in GexSe1-x glassescitations
- 2007Local structural variability and the intermediate phase window in network glassescitations
- 2005Ionic diffusion in quartz studied by transport measurements, SIMS and atomistic simulationscitations
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article
Search for a structural response to the intermediate phase in GexSe1-x glasses
Abstract
Atomic pair distribution functions (PDFs) obtained from high energy x-ray synchrotron radiation and x-ray absorption fine structure measurements were performed on 18 closely spaced compositions of chalcogenide glasses (Gex Se1-x with 0.15≤x≤0.40), which span the range of the floppy to rigid phase transition in these glasses. Structural parameters such as PDF peak widths, Debye-Waller factors from extended x-ray absorption fine structure, and the first sharp diffraction peak in S (Q) were extracted as a function of composition. These parameters smoothly evolve with composition, but there are no clear discontinuities or breaks in the slope associated with the appearance of the intermediate phase (IP). Therefore, these measurements do not confirm a structural origin for the IP.