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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Farjas, Jordi
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2022Chemical and Microstructural Nanoscale Homogeneity in Superconducting YBa2Cu3O7-x Films Derived from Metal-Propionate Fluorine-free Solutionscitations
- 2021High Performance of Superconducting YBa2Cu3O7 Thick Films Prepared by Single-Deposition Inkjet Printing
- 2020Ultrafast transient liquid assisted growth of high current density superconducting films
- 2020Ultrafast transient liquid assisted growth of high current density superconducting films
- 2020Relevance of the Formation of Intermediate Non-Equilibrium Phases in YBa2Cu3O7-x Film Growth by Transient Liquid-Assisted Growth
- 2020Elucidation of the decomposition reactions of low-fluorine YBa2Cu3O7-x precursors during film pyrolysis
- 2019Thermal decomposition of CuProp2: In-situ analysis of film and powder pyrolysiscitations
- 2018Epitaxial superconducting GdBa2Cu3O7−δ /Gd2O3 nanocomposite thin films from advanced low-fluorine solutionscitations
- 2015Thermal analysis of metal organic precursors for functional oxide preparation: Thin films versus powderscitations
- 2015The effect of volatiles on the measurement of the reaction heat by differential scanning calorimetrycitations
- 2013Thermal decomposition of barium trifluoroacetate thin filmscitations
- 2013Thermoanalytical study of the decomposition of yttrium trifluoroacetate thin filmscitations
- 2012Synthesis of nanocrystalline ceria thin films by low-temperature thermal decomposition of Ce-propionatecitations
- 2011Thermoanalytical study of the formation mechanism of yttria from yttrium acetatecitations
- 2009Characterization of amorphous and nanostructured Si films by differential scanning calorimetrycitations
- 2007Numerical model of solid phase transformations governed by nucleation and growth: Microstructure development during isothermal crystallizationcitations
- 2002Calorimetry of hydrogen desorption from a-Si nanoparticlescitations
- 2001Enhancement of oxidation rate of a-Si nanoparticles during dehydrogenationcitations
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article
Calorimetry of hydrogen desorption from a-Si nanoparticles
Abstract
The process of hydrogen desorption from amorphous silicon (a-Si) nanoparticles grown by plasma-enhanced chemical vapor deposition (PECVD) has been analyzed by differential scanning calorimetry (DSC), mass spectrometry, and infrared spectroscopy, with the aim of quantifying the energy exchanged. Two exothermic peaks centered at 330 and 410 °C have been detected with energies per H atom of about 50 meV. This value has been compared with the results of theoretical calculations and is found to agree with the dissociation energy of Si-H groups of about 3.25 eV per H atom, provided that the formation energy per dangling bond in a-Si is about 1.15 eV. It is shown that this result is valid for a-Si:H films, too.