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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Smetana, V.
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Topics
Publications (9/9 displayed)
- 2022Four ternary silicides in the La-Ni-Si system: from polyanionic layers to frameworkscitations
- 2021Crystal and electronic structures of the new ternary silicide Sc12Co41.8Si30.2citations
- 2021Investigation in the ternary Ta-Ni-P systemcitations
- 2020Metamagnetic transition, magnetocaloric effect and electronic structure of the rare-earth anti-perovskite SnOEu3citations
- 2020Magnetic phase transitions in Eu(Co1-x Nix)2-y As2 single crystalscitations
- 2020Ferromagnetic cluster-glass phase in Ca(Co1-xIrx)2-yAs2 crystalscitations
- 2019Helical antiferromagnetic ordering in EuNi1.95As2 single crystalscitations
- 2019Non-Fermi-liquid types of behavior associated with a magnetic quantum critical point in Sr(Co1-xNix)2As2 single crystalscitations
- 2018Enhanced moments of Eu in single crystals of the metallic helical antiferromagnet EuCo2-yAs2citations
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article
Ferromagnetic cluster-glass phase in Ca(Co1-xIrx)2-yAs2 crystals
Abstract
<p>Single crystals of Ca(Co1-xIrx)2-yAs2 with 0≤x≤0.35 and 0.10≤y≤0.14 have been grown using the self-flux technique and characterized by single-crystal x-ray diffraction (XRD), energy-dispersive x-ray spectroscopy, magnetization M, and magnetic susceptibility χ measurements versus temperature T, magnetic field H, and time t, and heat-capacity Cp(H,T) measurements. The XRD refinements reveal that all the Ir-substituted crystals crystallize in a collapsed-tetragonal structure as does the parent CaCo2-yAs2 compound. A small 3.3% Ir substitution for Co in CaCo1.86As2 drastically lowers the A-type antiferromagnetic (AFM) transition temperature TN from 52 to 23 K with a significant enhancement of the Sommerfeld electronic heat-capacity coefficient. The A-type AFM structure consists of ab-plane layers of spins ferromagnetically aligned along the c axis with AFM alignment of the spins in adjacent layers along this axis. The positive Weiss temperatures obtained from Curie-Weiss fits to the χ(T>TN) data indicate that the dominant magnetic interactions are ferromagnetic (FM) for all x. A magnetic phase boundary is inferred to be present between x=0.14 and x=0.17 from a discontinuity in the x dependencies of the effective moment and Weiss temperature in the Curie-Weiss fits. FM fluctuations that strongly increase with increasing x are also revealed from the χ(T) data. The magnetic ground state for x≥0.17 is a spin glass as indicated by hysteresis in χ(T) between field-cooled and zero-field-cooled measurements and from the relaxation of M in a small field that exhibits a stretched-exponential time dependence. The spin glass has a small FM component to the ordering and is hence inferred to be comprised of small FM clusters. The competing AFM and FM interactions along with crystallographic disorder associated with Ir substitution are inferred to be responsible for the development of a FM cluster-glass phase. A logarithmic T dependence of Cp at low T for x=0.14 is consistent with the presence of significant FM quantum fluctuations. This composition is near the T=0 boundary at x≈0.16 between the A-type AFM phase containing ferromagnetically-aligned layers of spins and the FM cluster-glass phase. </p>