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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Liu, Xi
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2023The selective oxidation of methane to methanol using in situ generated H 2 O 2 over palladium-based bimetallic catalysts †citations
- 2022Enhancing the Chemo-Enzymatic One-Pot Oxidation of Cyclohexane via in situ H2O2 production over supported Pd-based catalystscitations
- 2020Reduction and carburization of iron oxides for Fischer–Tropsch synthesiscitations
- 2019Promotion Mechanisms of Au Supported on TiO2 in Thermal- And Photocatalytic Glycerol Conversioncitations
- 2019Promotion Mechanisms of Au Supported on TiO 2 in Thermal- And Photocatalytic Glycerol Conversioncitations
- 2019Promotion mechanisms of Au supported on TiO2 in thermal- and photocatalytic glycerol conversioncitations
- 2012Current Status in Fabrication, Structural and Transport Property Characterization, and Theoretical Understanding of Bi2Te3 / Sb2Te3 Superlattice Systemscitations
- 2006The effects of small amounts of H2O, CO2 and Na2O on the partial melting of spinel Lherzolite in the system CaO-MgO-Al2O3-SiO2 ± H2O ± CO2 ± Na2O at 1·1GPacitations
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article
The effects of small amounts of H2O, CO2 and Na2O on the partial melting of spinel Lherzolite in the system CaO-MgO-Al2O3-SiO2 ± H2O ± CO2 ± Na2O at 1·1GPa
Abstract
<p>The effects of small amounts of H<sub>2</sub>O (<4wt % in the melt) on the multiply saturated partial melting of spinel lherzolite in the system CaO-MgO-Al<sub>2</sub>O<sub>3</sub>-SiO<sub>2</sub> ± Na<sub>2</sub>O ± CO<sub>2</sub> have been determined at 1·1GPa in the piston-cylinder apparatus. Electron microprobe analysis and Fourier transform infrared spectroscopy were used to analyse the experimental products. The effects of H<sub>2</sub>O are to decrease the melting temperature by 45°C per wt % H<sub>2</sub>O in the melt, to increase the Al<sub>2</sub>O<sub>3</sub> of the melts, decrease MgO and CaO, and leave SiO<sub>2</sub> approximately constant, with melts changing from olivine- to quartz-normative. The effects of CO<sub>2</sub> are insignificant at zero H<sub>2</sub>O, but become noticeable as H<sub>2</sub>O increases, tending to counteract the H<sub>2</sub>O. The interaction between H<sub>2</sub>O and CO<sub>2</sub> causes the solubility of CO<sub>2</sub> at vapour saturation to increase with increasing H<sub>2</sub>O, for small amounts of H<sub>2</sub>O. Neglect of the influence of CO<sub>2</sub> in some previous studies on the hydrous partial melting of natural peridotite may explain apparent inconsistencies between the results. The effect of small amounts of H<sub>2</sub>O on multiply saturated melt compositions at 1·1GPa is similar to that of K<sub>2</sub>O, i.e. increasing H<sub>2</sub>O or K<sub>2</sub>O leads to quartz-normative compositions, but increasing Na<sub>2</sub>O produces an almost opposite trend, towards nepheline-normative compositions.</p>