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Stutz, Elias
École Polytechnique Fédérale de Lausanne
in Cooperation with on an Cooperation-Score of 37%
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article
The path towards 1 µm monocrystalline Zn<sub>3</sub>P<sub>2</sub> films on InP: substrate preparation, growth conditions and luminescence properties
Abstract
<jats:title>Abstract</jats:title><jats:p>Semiconductors made with earth abundant elements are promising as absorbers in future large-scale deployment of photovoltaic technology. This paper reports on the epitaxial synthesis of monocrystalline zinc phosphide <jats:inline-formula><jats:tex-math><?CDATA $( {{{Z}}{{{n}}_3}{{{P}}_2}} )$?></jats:tex-math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"><mml:mfenced close=")" open="("><mml:mrow><mml:mrow><mml:mtext>Z</mml:mtext></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mtext>n</mml:mtext></mml:mrow><mml:mn>3</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mtext>P</mml:mtext></mml:mrow><mml:mn>2</mml:mn></mml:msub></mml:mrow></mml:mrow></mml:mfenced></mml:math><jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="jpenergyabf723ieqn1.gif" xlink:type="simple" /></jats:inline-formula> films using molecular beam epitaxy with thicknesses up to 1 <jats:italic>µ</jats:italic>m thickness on InP (100) substrates, as demonstrated by high resolution transmission electron microscopy and x-ray diffraction. We explain the mechanisms by which thick monocrystalline layers can form. We correlate the crystalline quality with the optical properties by photoluminescence at 12 K. Polycrystalline and monocrystalline films exhibit dissimilar photoluminescence below the bandgap at 1.37 and 1.30 eV, respectively. Band edge luminescence at 1.5 eV is only detected for monocrystalline samples. This work establishes a reliable method for fabricating high-quality <jats:inline-formula><jats:tex-math><?CDATA ${{Z}}{{{n}}_3}{{{P}}_2}$?></jats:tex-math><mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"><mml:mrow><mml:mtext>Z</mml:mtext></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mtext>n</mml:mtext></mml:mrow><mml:mn>3</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mtext>P</mml:mtext></mml:mrow><mml:mn>2</mml:mn></mml:msub></mml:mrow></mml:math><jats:inline-graphic xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="jpenergyabf723ieqn2.gif" xlink:type="simple" /></jats:inline-formula> thin films that can be employed in next generation photovoltaic applications.</jats:p>