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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vukašinović, Jelena
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Topics
Publications (13/13 displayed)
- 2023The influence of spark plasma sintering temperature on the properties of Sb-doped barium stannate ceramics
- 2023The crucial role of defect structure in understanding the electrical properties of spark plasma sintered antimony doped barium stannatecitations
- 2022Effect of the sintering technique on the properties of Sb-doped BaSnO3 ceramics
- 2022The defect structure and electrical properties of the spark plasma sintered antimony-doped barium stannate
- 2019Structural, microstructural and electrical properties of Sb-doped BaSnO3 ceramics
- 2019CuO-based nanoplatelets for humidity sensing application
- 2019The influence of sintering processing on microstructural, optical and electrical properties of zinc oxide ceramics doped with Al3+, B3+, Mg2+
- 2019Spark plasma sintering of conductive Sb-doped BaSnO3
- 2018Influence of sintering temperature and various atmospheres on structural and electrical properties of LaNi1-xNbxO3 (x = 0.005, 0.05)
- 2018Improvement of density and influence of Sb doping on structural properties of perovskite BaSnO3
- 2018Synthesis and characterization of Nb-doped lanthanum nickelate La(Ni,Nb)O3
- 2017Electrical properties of BaSn(1-x)SbxO3 ceramics materials
- 2016Synthesis, characterization and biological activity of platinum(II) and palladium(II) complexes with quinoline derivatives of thiosemicarbazones
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article
The crucial role of defect structure in understanding the electrical properties of spark plasma sintered antimony doped barium stannate
Abstract
<jats:title>Abstract</jats:title><jats:p>The influence of structural defects in spark plasma sintered BaSn<jats:sub>1-x</jats:sub>Sb<jats:sub>x</jats:sub>O<jats:sub>3</jats:sub> (BSSO, <jats:italic>x</jats:italic> = 0.00 and 0.08) ceramic samples on their electrical properties was investigated in the temperature range of 300–4 K. X-ray photoelectron spectroscopy (XPS) revealed the presence of point defects, primarily oxygen vacancies (V<jats:sub>O</jats:sub>) and mixed oxidation states of tin (Sn<jats:sup>2+</jats:sup>/Sn<jats:sup>4+</jats:sup>) in both samples. As a result, the undoped BSSO sample exibited a non-standard semiconductor behavior, retaining its temperature-dependent resistivity. The electrical resistivity of the doped samples was two orders of magnitude lower than that of the undoped sample. The presence of structural defects such as V<jats:sub>O</jats:sub>, mixed oxidation states of the constituent elements, and significant amounts of O<jats:sup>−</jats:sup> species make the electrical resistivity of the doped sample constant in the temperature range of 300–70 K, indicating heavily-doped semiconductor behavior.</jats:p>