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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bensch, Wolfgang
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2023Directed Dehydration of Na$_4$Sn$_2$S$_6$ ⋅ 5H$_2$O Generates the New Compound Na$_4$Sn$_2$S$_6$: Crystal Structure and Selected Propertiescitations
- 2023Exfoliablity, magnetism, energy storage and stability of metal thiophosphate nanosheets made in liquid medium.citations
- 2022A Combined Sodium Intercalation and Copper Extrusion Mechanism in the Thiophosphate Family: CuCrP2S6 as Anode Material in Sodium‐Ion Batteriescitations
- 2022Time-dependent investigation of a mechanochemical synthesis of bismuth telluride-based materials and their structural and thermoelectric propertiescitations
- 2022Multi‐Method Characterization of the High‐Entropy Spinel Oxide $Mn_{0.2}Co_{0.2}Ni_{0.2}Cu_{0.2}Zn_{0.2}Fe_2O_4$ : Entropy Evidence, Microstructure, and Magnetic Propertiescitations
- 2021The Coordination Polymer Cr(en) 2 As 2 VO 7 Consisting of Alternating VO 4 Tetrahedra and As 2 O 5 Handles Decorated by Cr 3+ Centered Complexes
- 2020CuCo2S4 deposited on TiO2: Controlling the pH Value Boosts Photocatalytic Hydrogen Evolutioncitations
- 2019Nanostructured tungsten sulfides: insights into precursor decomposition and the microstructure using X-ray scattering methodscitations
- 2019High-Pressure Sintering of Rhombohedral Cr2S3 Using Titanium-Zirconium-Molybdenum Toolscitations
- 2019High‐Pressure Sintering of Rhombohedral Cr2S3 Using TZM Toolscitations
- 2019Hydrothermal Synthesis, Characterization, and Sintering Behavior of Core-Shell Particles: A Principle Study on Lanthanum Strontium Cobaltite Coated with Nanosized Gadolinium Doped Ceriacitations
- 2019Hydrothermal Synthesis, Characterization, and Sintering Behavior of Core-Shell Particles: A Principle Study on Lanthanum Strontium Cobaltite Coated with Nanosized Gadolinium Doped Ceriacitations
- 2018Transition metal cations on the move: simultaneous operando X-ray absorption spectroscopy and X-ray diffraction investigations during Li uptake and release of a $mathrm{NiFe_{2}O_{4}/CNT}$ compositecitations
- 2018Hydrothermal Synthesis, Characterization, and Sintering Behavior of Core-Shell Particles: A Principle Study on Lanthanum Strontium Cobaltite Coated with Nanosized Gadolinium Doped Ceriacitations
- 2016Nucleation and Crystal Growth of a $V_{14}Sb_{8}O_{42}$ Cluster from a $V_{15}Sb_{6}O_{42}$ Polyoxovanadate: In-Situ XRD Studiescitations
- 2016Nanostructure, thermoelectric properties, and transport theory of V2VI3 and V2VI3/IV-VI based superlattices and nanomaterialscitations
- 2014Synthesis and thermal instability of high-quality Bi2Te3/Sb2Te3 superlattice thin film thermoelectricscitations
- 2012Current Status in Fabrication, Structural and Transport Property Characterization, and Theoretical Understanding of Bi2Te3 / Sb2Te3 Superlattice Systemscitations
- 2008Investigation of SnSe, SnSe2, and Sn2Se3 alloys for phase change memory applicationscitations
- 2006[C3H10NO]2[Sb4S7]: Solvothermal syntheses, crystal structures and properties of the first thioantimonates containing aminoalcohols as structure directorscitations
- 2006A study of the reactivity of elemental Cr/Se/Te thin multilayers using X-ray reflectometry, in situ X-ray diffraction and X-ray absorption spectroscopycitations
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article
Exfoliablity, magnetism, energy storage and stability of metal thiophosphate nanosheets made in liquid medium.
Abstract
<jats:title>Abstract</jats:title><jats:p>The family of antiferromagnetic layered metal hexathiohypo diphosphates, M2P2S6 represents a versatile class of materials, particularly interesting for fundamental studies on magnetic properties in low dimensional structures, and yet exhibiting great potential for a broad variety of applications including catalysis, energy storage and conversion, and spintronics. In this work, three representatives of this family of 2D materials (M = Fe, Ni, and Mn) are exfoliated in the liquid phase under inert conditions and the nanosheet’s properties are studied in detail for different sizes of all three compounds. Centrifugation-based size selection is performed for this purpose. The exfoliability and structural integrity of the nanosheets is studied by statistical AFM and TEM measurements. Further, we report size and thickness dependent optical properties and spectroscopic metrics for the average material dimensions in dispersion, as well as the nanomaterials’ magnetic response using a combination of cryo-Raman and SQUID measurements. Finally, the material stability is studied semi-quantitatively, using time and temperature dependent extinction and absorbance spectroscopy, enabling the determination of the materials’ half-life, portion of reacted substance and the macroscopic activation energy for the degradation.</jats:p>