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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bendounan, Azzedine
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Topics
Publications (15/15 displayed)
- 2023Dirac Fermions in Blue Phosphorene Monolayercitations
- 2023Dirac Fermions in Blue Phosphorene Monolayercitations
- 2023First steps of silicene growth on an insulating thin-film: effect of the substrate temperature
- 2023First steps of silicene growth on an insulating thin-film: effect of the substrate temperature
- 2021MoS2/PPy Nanocomposite as a Transducer for Electrochemical Aptasensor of Ampicillin in River Water
- 2021MoS2/PPy Nanocomposite as a Transducer for Electrochemical Aptasensor of Ampicillin in River Watercitations
- 2021Electron beam analysis induces Cl vacancy defects in a NaCl thin filmcitations
- 2020Evidence of new 2D material: Cu<sub>2</sub>Tecitations
- 2020Phosphorus Pentamers: Floating Nanoflowers form a 2D Networkcitations
- 2020Single-layer graphene on epitaxial FeRh thin filmscitations
- 2020Phase transition and thermal stability of epitaxial PtSe 2 nanolayer on Pt(111)citations
- 2020Evidence of new 2D material: Cu 2 Tecitations
- 2017Giant Rashba effect at the topological surface of PrGe revealing antiferromagnetic spintronicscitations
- 2016Case studies on the formation of chalcogenide self-assembled monolayers on surfaces and dissociative processescitations
- 2012Monitoring the formation of interface-confined mixture by photoelectron spectroscopycitations
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article
Evidence of new 2D material: Cu<sub>2</sub>Te
Abstract
The number of two-dimensional (2D) materials has grown steadily since the discovery of graphene. Each new 2D material demonstrated unusual physical properties offering a large flexibility in their tailoring for high-tech applications. Here, we report on the formation and characterization of an uncharted 2D material: 'Cu 2 Te alloy monolayer on Cu(111) surface'. We have successfully grown a 2D binary Te-Cu alloy using a straightforward approach based on chemical deposition method. Low electron energy diffraction (LEED) and scanning tunneling microscopy (STM) results reveal the existence of a well-ordered alloy monolayer characterized by (√3 × √3)R30 • superstructure, while the x-ray photoemission spectroscopy (XPS) measurements indicate the presence of single chemical environment of the Te atoms associated with the Te-Cu bonding. Analysis of the valence band properties by angle resolved photoemission spectroscopy (ARPES); in particular the electronic states close to the Fermi level suggests a strong hybridization between Te and Cu electronic states leading to an appearance of new dispersive bands localized at the surface alloy, which is confirmed by first-principles calculations. These bands are strongly influenced by the surface reconstruction and undergo a back-folding at the boundaries of the reduced surface Brillouin zone (SBZ). More interesting, a band gap of about 0.91 eV and a Rashba splitting in the conduction band are obtained. These findings taken together clearly prove the presence of 2D-type electron system within the Cu 2 Te alloy layer, which is promising for spintronic application.