| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Wolverson, Daniel
University of Bath
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Porous Structure Enhances the Longitudinal Piezoelectric Coefficient and Electromechanical Coupling Coefficient of Lead-Free (Ba0.85Ca0.15)(Zr0.1Ti0.9)O3citations
- 2024Spin-order-dependent magneto-elastic interactions in two dimensional antiferromagnetic MnPSe3 observed through Raman spectroscopycitations
- 2024Porous structure enhances the longitudinal piezoelectric coefficient and electromechanical coupling coefficient of lead‐free (Ba 0.85 Ca 0.15 )(Zr 0.1 Ti 0.9 )O 3citations
- 2023Exploring the Charge Density Wave Phase of 1T-TaSe2citations
- 2020Excitonic and lattice contributions to the charge density wave in 1T-TiSe2 revealed by a phonon bottleneckcitations
- 2020Phase behavior and substitution limit of mixed cesium-formamidinium lead triiodide perovskitescitations
- 2018Investigating nanostructures in carbon fibres using Raman spectroscopycitations
- 2017Strain-induced phonon shifts in tungsten disulfide nanoplatelets and nanotubescitations
- 2017Interfacial control in graphene- and transition metal dichalcogenide-polymer nanocomposites
- 2017Electronic band structure of ReS 2 by high-resolution angle-resolved photoemission spectroscopycitations
- 2017Electronic bandstructure and van der Waals coupling of ReSe2 revealed by high-resolution angle-resolved photoemission spectroscopycitations
- 2017Electronic band structure of ReS2 by high-resolution angle-resolved photoemission spectroscopycitations
- 2016Strain-induced phonon shifts in tungsten disulfide nanoplatelets and nanotubescitations
- 2016A comparison of the micromechanics of graphene- and transition metal dichalcogenide-nanocomposites
- 2014Raman spectra of monolayer, few-layer, and bulk ReSe 2 :An anisotropic layered semiconductorcitations
- 2014Raman spectra of monolayer, few-layer, and bulk ReSe2citations
- 2013Investigation of the sp3 structure of carbon fibres uUsing Uv-Raman spectroscopycitations
- 2012Porous silicon nanocrystals in a silica aerogel matrixcitations
- 2010Excitons in motion in II-VI semiconductorscitations
- 2010Carbon nanoparticle surface functionalisation: converting negatively charged sulfonate to positively charged sulfonamidecitations
- 2008Coherent Raman detected electron spin resonance spectroscopy of metalloproteins: linking electron spin resonance and magnetic circular dichroismcitations
- 2008Thin-film modified electrodes with reconstituted cellulose-PDDAC films for the accumulation and detection of triclosancitations
- 2000Band structure parameters of quaternary phosphide semiconductor alloys investigated by magneto-optical spectroscopy
Places of action
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article
Strain-induced phonon shifts in tungsten disulfide nanoplatelets and nanotubes
Abstract
The relationship between structure and properties has been followed for different nanoscale forms of tungsten disulfide (2H-WS2) namely exfoliated monolayer and few-layer nanoplatelets, and nanotubes. The similarities and differences between these nanostructured materials have been examined using a combination of optical microscopy, scanning and high-resolution transmission electron microscopy (SEM and HRTEM) and atomic force microscopy (AFM). Photoluminescence (PL) and Raman spectroscopy have also been used to distinguish between monolayer and few-layer material. Strain induced phonon shifts have been followed from the changes in the positions of the A1g and E2g1 Raman bands during uniaxial deformation. This has been modelled for monolayer using density functional theory (DFT) with excellent agreement between the measured and predicted behaviour. It has been found that as the number of WS2 layers increases for few-layer crystals or nanotubes, the A1g mode hardens whereas the E2g1 mode softens. This is believed to be due to the A1g mode, which involves out of plane atomic movements, being constrained by the increasing number of WS2 layers whereas easy sliding reduces stress transfer to the individual layers for the E2g1 mode, involving only in-plane vibrations. This finding has enabled the anomalous phonon shift behaviour in earlier pressure measurements on WS2 to be resolved, as well as similar effects in other transition metal dichalcogenides, such as molybdenum disulfide (MoS2), to be explained.