Materials Map

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (6/6 displayed)

  • 2021Corrosion resistance, nano-mechanical properties, and biocompatibility of Mg-plasma-implanted and plasma-etched Ta/TaN hierarchical multilayered coatings on the nitrided AZ91 Mg alloy8citations
  • 2021Enhanced corrosion resistance, antibacterial properties, and biocompatibility by hierarchical hydroxyapatite/ciprofloxacin-calcium phosphate coating on nitrided NiTi alloy37citations
  • 2021Effects of the tantalum intermediate layer on the nanomechanical properties and biocompatibility of nanostructured tantalum/tantalum nitride bilayer coating deposited by magnetron sputtering on the nickel titanium alloy12citations
  • 2020EIS and noise study of zirconia-alumina- benzotriazole nano-composite coating applied on Al2024 by the sol-gel method18citations
  • 2019Nano-mechanical properties of zirconia-alumina-benzotriazole nano-composite coating deposited on Al2024 by the sol-gel method12citations
  • 2019Effects of Benzotriazole on nano-mechanical properties of zirconia-alumina-Benzotriazole nanocomposite coating deposited on Al 2024 by the sol-gel method14citations

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Shanaghi, Ali
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Ahmadian, Zahra
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Saedi, Hashem
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Rafie, Mahdi
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2019

Co-Authors (by relevance)

  • Shanaghi, Ali
  • Ahmadian, Zahra
  • Saedi, Hashem
  • Rafie, Mahdi
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article

Corrosion resistance, nano-mechanical properties, and biocompatibility of Mg-plasma-implanted and plasma-etched Ta/TaN hierarchical multilayered coatings on the nitrided AZ91 Mg alloy

  • Shanaghi, Ali
  • Souri, Ali Reza
Abstract

A tantalum/tantalum nitride (Ta/TaN) multilayered coating is deposited on plasma-nitridedAZ91 Mg alloy. The top TaN layer undergoes O<sub>2</sub> + Ar plasma etching to improve the antibacterial properties and Mg plasma immersion ion implantation (MgPIII) is performed to enhance the biocompatibility and wound healing capability. A uniform, compact, homogeneous, and columnar nanostructured MgPIII and plasma-etched TaN layer with a cluster size of about 17 nm, surface roughness of 0.28 nm, and needle morphology is observed. Although, plasma etching increases the corrosion current density (<i>i</i> <sub>corr)</sub> from 0.02 to 0.19 µA cm<sup>-2</sup> due to larger surface roughness and different potentials between sharp points and smooth points, MgPIII decreases <i>i</i> <sub>corr</sub> from 0.19 to 0.02 µA cm-2 besides a more positive corrosion potential. The amounts of Mg<sup>+2</sup> released to the simulated body fluid (SBF) diminishes from 89.63 ± 0.54 to 60.30 ± 0.47 mg l<sup>-1</sup> cm<sup>-2 </sup>indicating improved corrosion resistance. Under fever conditions (40 °C), <i>i</i> <sub>corr </sub>decreases by 63%, but the open circuit potential does not change due to the constant chemical composition of the surface as well as thicker double layer and less defects, as confirmed by the larger amount of Mg<sup>+2</sup> of 71.49 ± 0.22 mg<sup> l</sup>-1 cm<sup>-2</sup> leached to the SBF. In the self-healing process which occurs via the reactions between the tantalum intermediate layer and electrolytes and penetrating ions through the defects as well as formation of oxide compounds, creation and propagation of defects are deterred as shown the 24 h destructive polarization test in SBF. The combination of plasma etching and MgPIII enhance not only the bacterial resistance and biocompatibility of the super-hard TaN layer by providing the rougher surface on TaN-P-Mg, but also the nano-mechanical properties and anticorrosion properties. As a result, the hardness increases by 7%, elastic modulus decreases by 19%, and the stiffness increases by 21%.

Topics
  • density
  • impedance spectroscopy
  • surface
  • compound
  • cluster
  • corrosion
  • laser emission spectroscopy
  • nitride
  • hardness
  • chemical composition
  • defect
  • current density
  • biocompatibility
  • tantalum
  • plasma etching