| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Shanaghi, Ali
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2021Enhanced corrosion resistance and reduced cytotoxicity of the AZ91 Mg alloy by plasma nitriding and a hierarchical structure composed of ciprofloxacin-loaded polymeric multilayers and calcium phosphate coatingcitations
- 2021Corrosion resistance, nano-mechanical properties, and biocompatibility of Mg-plasma-implanted and plasma-etched Ta/TaN hierarchical multilayered coatings on the nitrided AZ91 Mg alloycitations
- 2021Enhanced corrosion resistance, antibacterial properties, and biocompatibility by hierarchical hydroxyapatite/ciprofloxacin-calcium phosphate coating on nitrided NiTi alloycitations
- 2021Effects of the tantalum intermediate layer on the nanomechanical properties and biocompatibility of nanostructured tantalum/tantalum nitride bilayer coating deposited by magnetron sputtering on the nickel titanium alloycitations
- 2020EIS and noise study of zirconia-alumina- benzotriazole nano-composite coating applied on Al2024 by the sol-gel methodcitations
- 2019Effect of Ti interlayer on corrosion behavior of nanostructured Ti/TiN multilayer coating deposited on TiAl<sub>6</sub>V<sub>4</sub>citations
- 2019Improved corrosion behavior of DLC-coated AZ91 Mg
- 2019Nano-mechanical properties of zirconia-alumina-benzotriazole nano-composite coating deposited on Al2024 by the sol-gel methodcitations
- 2019Effects of Benzotriazole on nano-mechanical properties of zirconia-alumina-Benzotriazole nanocomposite coating deposited on Al 2024 by the sol-gel methodcitations
- 2018Effects of silica and Ag on the electrochemical behavior of titania-based nanocomposite coatings deposited on 2024 aluminum alloy by the sol-gel methodcitations
- 2018Improving of tribology properties of TiAl6V4 with nanostructured Ti/TiN-multilayered coating deposited by high-vacuum magnetron sputteringcitations
- 2017Effect of Inhibitor Agents Addition on Corrosion Resistance Performance of Titania Sol–Gel Coatings Applied on 304 Stainless Steelcitations
- 2017Corrosion behavior of reactive sputtered Ti/TiN nanostructured coating and effects of intermediate titanium layer on self-healing propertiescitations
- 2017Nano mechanical and wear properties of multi-layer Ti/TiN coatings deposited on Al 7075 by high-vacuum magnetron sputteringcitations
- 2012Effect of plasma CVD operating temperature on nanomechanical properties of TiC nanostructured coating investigated by atomic force microscopycitations
- 2012Effects of duty cycle on microstructure and corrosion behavior of TiC coatings prepared by DC pulsed plasma CVDcitations
- 2011Improved tribological properties of TiC with porous nanostructured TiO 2 intermediate layercitations
Places of action
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article
Corrosion resistance, nano-mechanical properties, and biocompatibility of Mg-plasma-implanted and plasma-etched Ta/TaN hierarchical multilayered coatings on the nitrided AZ91 Mg alloy
Abstract
A tantalum/tantalum nitride (Ta/TaN) multilayered coating is deposited on plasma-nitridedAZ91 Mg alloy. The top TaN layer undergoes O<sub>2</sub> + Ar plasma etching to improve the antibacterial properties and Mg plasma immersion ion implantation (MgPIII) is performed to enhance the biocompatibility and wound healing capability. A uniform, compact, homogeneous, and columnar nanostructured MgPIII and plasma-etched TaN layer with a cluster size of about 17 nm, surface roughness of 0.28 nm, and needle morphology is observed. Although, plasma etching increases the corrosion current density (<i>i</i> <sub>corr)</sub> from 0.02 to 0.19 µA cm<sup>-2</sup> due to larger surface roughness and different potentials between sharp points and smooth points, MgPIII decreases <i>i</i> <sub>corr</sub> from 0.19 to 0.02 µA cm-2 besides a more positive corrosion potential. The amounts of Mg<sup>+2</sup> released to the simulated body fluid (SBF) diminishes from 89.63 ± 0.54 to 60.30 ± 0.47 mg l<sup>-1</sup> cm<sup>-2 </sup>indicating improved corrosion resistance. Under fever conditions (40 °C), <i>i</i> <sub>corr </sub>decreases by 63%, but the open circuit potential does not change due to the constant chemical composition of the surface as well as thicker double layer and less defects, as confirmed by the larger amount of Mg<sup>+2</sup> of 71.49 ± 0.22 mg<sup> l</sup>-1 cm<sup>-2</sup> leached to the SBF. In the self-healing process which occurs via the reactions between the tantalum intermediate layer and electrolytes and penetrating ions through the defects as well as formation of oxide compounds, creation and propagation of defects are deterred as shown the 24 h destructive polarization test in SBF. The combination of plasma etching and MgPIII enhance not only the bacterial resistance and biocompatibility of the super-hard TaN layer by providing the rougher surface on TaN-P-Mg, but also the nano-mechanical properties and anticorrosion properties. As a result, the hardness increases by 7%, elastic modulus decreases by 19%, and the stiffness increases by 21%.