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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Madsen, Peter Jeppe
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Preparation of Block Copolymer-Stabilized Microspheres from Commercial Plastics and Their Use as Microplastic Proxies in Degradation Studiescitations
- 2023Enhancement of viscoelastic property of MABS processed by melt compounding and injection moldingcitations
- 2023Antimicrobial silicone skin adhesives facilitated by controlled octenidine release from glycerol compartmentscitations
- 2023Synthesis of poly(ethylene glycol)-co-poly(caprolactone) di- and triblock copolymers and effect of architecture, dispersity and end-functionalisation on their aqueous self-assemblycitations
- 2022One reaction to make highly stretchable or extremely soft silicone elastomers from easily available materialscitations
- 2021Toward a Design for Flowable and Extensible Ionomers: An Example of Diamine-Neutralized Entangled Poly(styrene-co-4-vinylbenzoic acid) Ionomer Meltscitations
- 2021Frequency dependent behavior of silicone slide-ring elastomers
- 2021Novel polyrotaxane cross-linkers as a versatile platform for slide-ring siliconecitations
- 2021Super-stretchable silicone elastomer applied in low voltage actuatorscitations
- 2020Linear Viscoelastic and Nonlinear Extensional Rheology of Diamine Neutralized Entangled Poly(styrene-co-4-vinylbenzoic acid) Ionomer Melts
- 2020Utilizing slide-ring cross-linkers in polysiloxane networks for softer dielectric elastomer actuatorscitations
- 2019Rheological and mechanical properties of polystyrene with hydrogen bonding
- 2019Incorporating polyrotaxane materials in dielectric elastomer actuators
- 2018Enhancing the electro-mechanical properties of polydimethylsiloxane elastomers through blending with poly(dimethylsiloxane-co-methylphenylsiloxane) copolymerscitations
- 2018Enhancing the electro-mechanical properties of polydimethylsiloxane elastomers through blending with poly(dimethylsiloxane-co-methylphenylsiloxane) copolymers Acknowledgments
- 2018Fabrication of microstructured binary polymer brush "corrals" with integral pH sensing for studies of proton transport in model membrane systemscitations
- 2008Supercritical fluids applied to the sol–gel process for preparation of AEROMOSILS/palladium particle nanocomposite catalystcitations
- 2008Facile Synthesis of Well-Defined Hydrophilic Methacrylic Macromonomers Using ATRP and Click Chemistrycitations
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article
Novel polyrotaxane cross-linkers as a versatile platform for slide-ring silicone
Abstract
Slide-ring elastomers have garnered a lot of interest for their potential use in dielectric elastomer actuators due to their intrinsically soft nature and high elasticity. However, the use of sliding cross-linkers has been constrained by their low miscibility with commonly used elastomer precursors and the specialized curing chemistries that are necessary for incorporating them into networks. Here, we have presented a method to produce vinyl functional polyrotaxane cross-linkers that are compatible with polysiloxanes and can be processed by industrially scalable methods. The sliding silicone films that were fabricated with these novel cross-linkers were highly extensible (>350%) and did not exhibit strain hardening even at high elongation. The composite films also retained the favorable dielectric properties of silicone elastomers such as the characteristic low dielectric loss. The modified polyrotaxanes present a robust platform for producing a new class of sliding silicone elastomers with well-defined networks structures.