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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zlotnikov, Igor
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (19/19 displayed)
- 2023In Situ Nanoindentation at Elevated Humiditiescitations
- 2020Natural hybrid silica/protein superstructure at atomic resolutioncitations
- 2019Morphological and textural evolution of the prismatic ultrastructure in mollusc shellscitations
- 2017Nano-scale modulus mapping of biological composite materials: Theory and practicecitations
- 2017Mesocrystalline calcium silicate hydrate : a bioinspired route toward elastic concrete materialscitations
- 2016Gas barrier properties of bio-inspired Laponite–LC polymer hybrid filmscitations
- 2016Inherent Role of Water in Damage Tolerance of the Prismatic Mineral–Organic Biocomposite in the Shell of Pinna Nobiliscitations
- 2015Micro- and nano-structural details of a spider's filter for substrate vibrationscitations
- 2015Characterizing moisture-dependent mechanical properties of organic materialscitations
- 2015Electron microscope analyses of the bio-silica basal spicule from the Monorhaphis chuni spongecitations
- 2015Eshelby Twist as a Possible Source of Lattice Rotation in a Perfectly Ordered Protein/Silica Structure Grown by a Simple Organismcitations
- 2014A spider's biological vibration filtercitations
- 2014A Perfectly Periodic Three-Dimensional Protein/Silica Mesoporous Structure Produced by an Organismcitations
- 2014Hierarchically Structured Vanadium Pentoxide-Polymer Hybrid Materialscitations
- 2014Composition and Mechanical Properties of a Protein/Silica Hybrid Material Forming the Micron-Thick Axial Filament in the Spicules of Marine Spongescitations
- 2014Mesoporous silica: a perfectly periodic three-dimensional protein/silica mesoporous structure produced by an organism (adv. Mater. 11/2014).citations
- 2014Nanostructure of Biogenic Calcite and Its Modification under Annealing: Study by High-Resolution X-ray Diffraction and Nanoindentationcitations
- 2014Self-similar mesostructure evolution of the growing mollusc shell reminiscent of thermodynamically driven grain growthcitations
- 2013Structural and mechanical properties of the arthropod cuticlecitations
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article
Gas barrier properties of bio-inspired Laponite–LC polymer hybrid films
Abstract
Bio-inspired Laponite (clay)-liquid crystal (LC) polymer composite materials with high clay fractions (>80%) and a high level of orientation of the clay platelets, i.e. with structural features similar to the ones found in natural nacre, have been shown to exhibit a promising behavior in the context of reduced oxygen transmission. Key characteristics of these bio-inspired composite materials are their high inorganic content, high level of exfoliation and orientation of the clay platelets, and the use of a LC polymer forming the organic matrix in between the Laponite particles. Each single feature may be beneficial to increase the materials gas barrier property rendering this composite a promising system with advantageous barrier capacities. In this detailed study, Laponite/LC polymer composite coatings with different clay loadings were investigated regarding their oxygen transmission rate. The obtained gas barrier performance was linked to the quality, respective Laponite content and the underlying composite micro-and nanostructure of the coatings. Most efficient oxygen barrier properties were observed for composite coatings with 83% Laponite loading that exhibit a structure similar to sheet-like nacre. Further on, advantageous mechanical properties of these Laponite/LC polymer composites reported previously give rise to a multifunctional composite system.