• Sudhakar, Y. N.
• Raviprakash, Y.
• Chandrika, Yadav K.
• Pramitha, A.
• Chakraborty, Shamik
• Bhat, Badekai Ramachandra
• Ravikumar, Abhilash

Abstract

<jats:title>Abstract</jats:title><jats:p>The remarkable storage performance of manganese oxide (Mn3O4) makes it an appealing option for use as electrodes in electrochemical capacitors. However, the storage kinetics were significantly influenced by the mass loading of the electrode. Herein, we have inspected the dependency of mass loading on the storage performance of the spray pyrolyzed Mn3O4 thin film electrodes along with the correlation of structural and morphological characteristics. X-ray diffraction and Raman spectroscopic studies proven the formation of spinel Mn3O4 with a tetragonal structure. Morphological analysis revealed that all films exhibited fibrous structures with interconnected patterns at higher mass loadings. Moreover, the surface roughness and wettability of the electrode surface were influenced by variations in mass loading. Notably, thin-film electrode with a mass loading of 0.4 mg/cm2 exhibited the highest specific capacitance value of 168 F/g at 5 mV/s in a three-electrode system. Further, electrochemical impedance spectroscopic studies showed that there were noticeable changes in the capacitive behaviour of the electrode with respect to variations in mass loading. Moreover, the Dunn approach was employed to differentiate the underlying storage mechanism of the Mn3O4 electrode. Additionally, first-principles Density Functional Theory (DFT) studies were carried out in connection with the experimental study to comprehend the structure and electronic band structure of Mn3O4. This study underscores the critical importance of mass loading for enhancing the storage performance of Mn3O4 thin-film electrodes.&amp;#xD;</jats:p>

Topics

• density
• surface
• x-ray diffraction
• theory
• thin film
• density functional theory
• Manganese
• band structure