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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Saeed, Abdu
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Publications (6/6 displayed)
- 2023Enhancement of the structural, optical, and dispersion performance of polyvinyl alcohol via coronene additive for optoelectronic applicationscitations
- 2023Fabrication and characterizations of nanocomposite flexible films of ZnO and polyvinyl chloride/poly(N-vinyl carbazole) polymers for dielectric capacitors
- 2023Radiographic testing of 3D-printed thermoplastics using Am-241 as a gamma-ray sourcecitations
- 2023Synthesis of polyaniline/spinel ferrites core-shell nanocomposites via sucrose auto-combustion and in situ polymerization
- 2023Incorporated <scp>TiO<sub>2</sub></scp> nanoparticles into <scp>PVC</scp>/<scp>PMMA</scp> polymer blend for enhancing the optical and electrical/dielectric properties: Hybrid nanocomposite films for flexible optoelectronic devicescitations
- 2023An insight into the role of titanium oxide nanofiller on the structural, optical, electrical, and dielectric characteristics of PS/PVK compositecitations
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article
Enhancement of the structural, optical, and dispersion performance of polyvinyl alcohol via coronene additive for optoelectronic applications
Abstract
<jats:title>Abstract</jats:title><jats:p>Composite films made of polyvinyl alcohol (PVA) filled with various coronene concentrations were fabricated via the solution casting method. Several characterization techniques were used to examine the prepared samples. The x-ray diffraction study shows decreasing semi-crystalline properties in PVA/coronene composites with increasing coronene levels, thereby improving charge carrier mobility and enhancing conductivity. The alterations in the chemical functional groups of the PVA/coronene composites were explored using Fourier-transform infrared spectroscopy (FTIR). The impact of coronene molecules on the optical characteristics of PVA was investigated in the spectral ranges of 190-2500 nm. PVA/coronene composite exhibits higher UV blocking in the 190-400 nm wavelength range, suitable for UV notch filters like laser blocking filters. By increasing the coronene filling ratio from 0 wt% to 3 wt%, both the indirect and direct optical band-gap of PVA films decreased from 5.19 eV and 5.77 eV to 3.85 eV and 5.18 eV, respectively. The single oscillator model (Wemple-DiDomenico) was used to explain the refractive index dispersion region. The extracted values of dispersion energy (E<jats:sub>d</jats:sub>), oscillator energy (E<jats:sub>o</jats:sub>), dielectric constant at infinite frequency (<jats:italic>ε</jats:italic><jats:sub>∞</jats:sub>), and lattice dielectric constant (<jats:italic>ε</jats:italic><jats:sub>L</jats:sub>) of PVA/coronene composite samples increased from 0.78 eV, 2.41 eV, 1.32 and 1.41 to 13.44 eV, 12.22 eV 2.10 and 2.13, respectively. These changes in dispersion parameters are due to cross-linking between the PVA polymeric matrix and the coronene. As a result of these improvements, PVA/coronene films could be applied to flexible packaging applications and optoelectronic devices like solar cells or light-emitting diodes.</jats:p>