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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Barjon, Julien
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2024Benchmarking the integration of hexagonal boron nitride crystals and thin films into graphene-based van der Waals heterostructurescitations
- 2023Vertical pin diodes on large freestanding (100) diamond film
- 2023Pseudo-delta phosphorus doped diamond
- 2020Heteroepitaxial growth of sp 2 -hybridized boron nitride multilayer on nickel substrates by CVD: the key role of the substrate orientationcitations
- 2020Production and processing of graphene and related materials
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materials
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2019Advanced synthesis of highly crystallized hexagonal boron nitride by coupling polymer-derived ceramics and spark plasma sintering processes—influence of the crystallization promoter and sintering temperaturecitations
- 2018Hybrid halide perovskites: a new semiconductor for photovoltaics and light emission
- 2017Angular resolved electron energy loss spectroscopy in hexagonal boron nitride
- 2017Angle-resolved electron energy loss spectroscopy in hexagonal boron nitridecitations
- 2017Surface effects on exciton diffusion in non polar ZnO/ZnMgO heterostructurescitations
- 2014Substitutional phosphorus incorporation in nanocrystalline CVD diamond thin filmscitations
- 2008Correlation Between Microstructure and Optical Properties of ZnO Based Nanostructures Grown by MOCVD
- 2008Stability of B-H and B-D complexes in diamond under electron beam excitationcitations
Places of action
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article
Advanced synthesis of highly crystallized hexagonal boron nitride by coupling polymer-derived ceramics and spark plasma sintering processes—influence of the crystallization promoter and sintering temperature
Abstract
International audience ; Hexagonal boron nitride nanosheets (BNNSs) are promising 2D materials due to their exceptional chemical and thermal stabilities together with their electrical insulation properties. A combined synthesis method involving the polymer-derived ceramics (PDCs) route and the spark plasma sintering (SPS) process is proposed, leading to well-crystallized and pure layered h-BN crystals, prone to be exfoliated into large BNNSs. Here we focus more specifically on the influence of two key parameters of the process to be optimized: the Li3N concentration (0–10 wt%) and the SPS temperature (1200 °C–1950 °C). The presence of Li3N, added as crystal promoter in the pre-ceramic powder, significantly improves the crystallinity level of the product, as evidenced by XRD, SEM and Raman spectrometry. SPS temperature strongly modifies the size of the resulting h-BN flakes. The influence of SPS temperature on both purity and crystallinity is studied using cathodoluminescence. h-BN flakes larger than 200 μm2 (average flake area) are obtained. Few-layered BNNSs are successfully isolated, through exfoliation process.