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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Reduto, Igor
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Publications (4/4 displayed)
- 2023Bottom-up approach to the formation of bi-resonant glass-metal nanocomposite
- 2021Controlled metallization of ion-exchanged glasses by thermal polingcitations
- 2019Self-assembled silver nanoparticles in glass microstructured by poling for SERS applicationcitations
- 2019Relief micro- and nanostructures by the reactive ion and chemical etching of poled glassescitations
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article
Controlled metallization of ion-exchanged glasses by thermal poling
Abstract
We present studies of the formation of silver nanoparticles (NPs) in silver-sodium ion-exchanged glasses by a combination of thermal poling and nanosecond pulsed laser irradiation at 355 nm. In poling, silver ions drift deeper into the glass and become separated from the glass surface by a poled layer depleted in cations. Performed measurements have indicated poling-induced broadening of silver ions depth distribution. Laser irradiation reduces silver ions to atomic silver via breaking silver-non-bridging oxygen (NBO) bonds, extraction of electrons from the NBO atoms and capturing these electrons and electrons generated via multi-photon absorption in the glass by silver ions. The depleted layer limits diffusion of silver atom towards glass surface and, as a consequence, formation of silver NPs on the surface of poled glasses. It is shown that thermal poling mode allows one to control formation of silver NPs of glass surface.