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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Monnier, Judith
Agence Nationale de la Recherche
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (35/35 displayed)
- 2024High-temperature stability of chemically architectured high entropy alloys studied by X-ray diffraction and diffusion modellingcitations
- 2024Liquid-phase shear exfoliation of graphite and its application as corrosion protection coating on aluminum substrate
- 2024AsTe 3 : A novel crystalline semiconductor with ultralow thermal conductivity obtained by congruent crystallization from parent glasscitations
- 2023Investigations of the Mn–Ni–Sm ternary system by means of anomalous X-ray diffraction, X-ray absorption and DFT calculations
- 2022Quantification of stacking faults in ANiy (A = rare earth or Mg, y = 3.5 and 3.67) hydrogen storage materialscitations
- 2022Chemically architectured alloys: How interphase width influences the strengtheningcitations
- 2020Investigation of H Sorption and Corrosion Properties of Sm2MnxNi7−x (0 ≤ x < 0.5) Intermetallic Compounds Forming Reversible Hydridescitations
- 2020Correlations between stacked structures and weak itinerant magnetic properties of La2−xYxNi7 compoundscitations
- 2020Chemical architecturation of high entropy alloys through powder metallurgycitations
- 2018Improved ZT in ball‐milled and spark plasma sintered Cu 15 As 30 Te 55 glass ceramicscitations
- 2018Stabilization of Metastable Thermoelectric Crystalline Phases by Tuning the Glass Composition in the Cu–As–Te Systemcitations
- 2018Stabilization of Metastable Thermoelectric Crystalline Phases by Tuning the Glass Composition in the Cu–As–Te Systemcitations
- 2017Thermoelectric properties and stability of glasses in the Cu-As-Te systemcitations
- 2017Thermoelectric properties and stability of glasses in the Cu-As-Te systemcitations
- 2017Stabilization of Metastable Thermoelectric Crystalline Phases by Tuning the Glass Composition in the Cu–As–Te Systemcitations
- 2016Relationship between H2 sorption properties and aqueous corrosion mechanisms in A2Ni7 hydride forming alloys (A = Y, Gd or Sm)citations
- 2016Relationship between H2 sorption properties and aqueous corrosion mechanisms in A2Ni7 hydride forming alloys (A = Y, Gd or Sm)citations
- 2016Fast and scalable preparation of tetrahedrite for thermoelectrics via glass crystallizationcitations
- 2016Low-Temperature Transport Properties of Bi-Substituted b-As2Te3 Compoundscitations
- 2016Electronic structure, low-temperature transport and thermodynamic properties of polymorphic b-As2Te3citations
- 2016Low-Temperature Transport Properties of Bi-Substituted β-As 2 Te 3 Compoundscitations
- 2016Electronic structure, low-temperature transport and thermodynamic properties of polymorphic β-As 2 Te 3citations
- 2015Electrochemical Properties and Dissolution Mechanism of A2Ni7 Hydrides (A=Y, Gd, La–Sm)citations
- 2015Structural and Hydrogen Storage Properties of Y<inf>2</inf>Ni<inf>7</inf> Deuterides Studied by Neutron Powder Diffractioncitations
- 2015Effective medium theory based modeling of the thermoelectric properties of composites: comparison between predictions and experiments in the glass-crystal composite system Si10As15Te75–Bi0.4Sb1.6Te3citations
- 2015Electrochemical Properties and Dissolution Mechanism ofA2Ni7 Hydrides (A=Y, Gd, La–Sm)citations
- 2015Structural and Hydrogen Storage Properties of Y 2 Ni 7 Deuterides Studied by Neutron Powder Diffractioncitations
- 2015Effective medium theory based modeling of the thermoelectric properties of composites: comparison between predictions and experiments in the glass-crystal composite system Si 10 As 15 Te 75 –Bi 0.4 Sb 1.6 Te 3citations
- 2015Structural and hydrogen storage properties of Y2Ni7 deuterides studied by neutron powder diffractioncitations
- 2014The benefit of the European User Community from transnational access to national radiation facilitiescitations
- 2013A comprehensive study of the crystallization of Cu-As-Te glasses: microstructure and thermoelectric propertiescitations
- 2013Mechanical milling and SPS used to obtain GeS2-βGeS2 infrared glass-ceramiccitations
- 2013Thermal stability and thermoelectric properties of Cu x As 40−x Te 60−y Se y semiconducting glassescitations
- 2012Investigation of the Mechanisms Involved in the Sintering of Chalcogenide Glasses and the Preparation of Glass-Ceramics by Spark Plasma Sinteringcitations
- 2011An innovative approach to develop highly performant chalcogenide glasses and glass-ceramics transparent in the infrared range.citations
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article
Correlations between stacked structures and weak itinerant magnetic properties of La2−xYxNi7 compounds
Abstract
International audience ; Hexagonal La2Ni7 and rhombohedral Y2Ni7 are weak itinerant antiferromagnet (wAFM) and ferromagnet (wFM), respectively. To follow the evolution between these two compounds, the crystal structure and magnetic properties of A2B7 intermetallic compounds (A = La, Y, B = Ni) have been investigated combining X-ray powder diffraction and magnetic measurements. The La2-xYxNi7 intermetallic compounds with 0 ≤ x ≤ 1 crystallize in the hexagonal Ce2Ni7-type structure with Y preferentially located in the [A2B4] units. The compounds with larger Y content (1.2 ≤ x < 2) crystallize in both hexagonal and rhombohedral (Gd2Co7-type) structures with a substitution of Y for La in both [A2B4] and [AB5] units. Y2Ni7 crystallizes in the rhombohedral structure only. The average cell volume decreases linearly versus Y content, whereas the c/a ratio presents a minimum at x = 1 due to geometric constrains. The magnetic properties are strongly dependent on the structure type and the Y content. La2Ni7 displays a complex metamagnetic behavior with split AFM peaks. Compounds with x = 0.25 and 0.5 display a wAFM ground state and two metamagnetic transitions, the first one towards an intermediate wAFM state and the second one towards a FM state. TN and the second critical field µ0Hc2 increase with the Y content, indicating a stabilization of the AFM state. LaYNi7, which is as the boundary between the two structure types, presents a very wFM state at low field and an AFM state as the applied field increases. All the compounds with x > 1, and which contains a rhombohedral phase are wFM with TC = 53(2) K. In addition to the experimental studies, first principles calculations using spin polarization have been performed to interpret the evolution of structural phase stability for 0 ≤ x ≤ 2.