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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Masař, Milan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Nesting BiVO<sub>4</sub> nanoislands in ZnO nanodendrites by two-step electrodeposition for efficient solar water splittingcitations
- 2024Investigation of Combined Aging and Mullins Stress Softening of Rubber Nanocompositescitations
- 2023Boosting photocatalytic degradation of estrone hormone by silica-supported g-C3N4/WO3 using response surface methodology coupled with Box-Behnken design
- 2022Boosting the Photoelectrochemical Performance of Au/ZnO Nanorods by Co-Occurring Gradient Doping and Surface Plasmon Modificationcitations
- 2021Reduced percolation threshold of conductive adhesive through nonuniform filler localization: Monte Carlo simulation and experimental studycitations
- 2021Excellent, Lightweight and Flexible Electromagnetic Interference Shielding Nanocomposites Based on Polypropylene with MnFe2O4 Spinel Ferrite Nanoparticles and Reduced Graphene Oxidecitations
- 2021High-Performance, Lightweight, and Flexible Thermoplastic Polyurethane Nanocomposites with Zn2+ substituted CoFe2O4 Nanoparticles and Reduced Graphene Oxide as Shielding Material against Electromagnetic Pollutioncitations
- 2020Polypropylene Nanocomposite Filled with Spinel Ferrite NiFe2O4 Nanoparticles and In-Situ Thermally-Reduced Graphene Oxide for Electromagnetic Interference Shielding Applicationcitations
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article
Nesting BiVO<sub>4</sub> nanoislands in ZnO nanodendrites by two-step electrodeposition for efficient solar water splitting
Abstract
<jats:title>Abstract</jats:title><jats:p>Photoanodes with a large electrochemically active surface area, rapid charge transfer, and broadband light harvesting capacity are required to maximize the photoelectrochemical (PEC) water splitting performance. To address these features, we demonstrate that 3D hierarchal ZnO nanodendrites (NDs) can be sensitized with BiVO<jats:sub>4</jats:sub> nanoislands by chemical and thermal treatments of electrodeposited Bi metal films. The flat band measurements and optical characterization suggested that the resulting heterojunction had type-II band alignment with a viable charge transfer from BiVO<jats:sub>4</jats:sub> to ZnO NDs. In parallel, PL analysis revealed inhibition of the charge recombination rate by the electron transfer between BiVO<jats:sub>4</jats:sub> and ZnO NDs. Upon AM 1.5 G illumination, BiVO<jats:sub>4</jats:sub>/ZnO NDs heterojunction yielded the highest photocurrent efficiency (0.15 mA·cm<jats:sup>−2</jats:sup> at 1.2 V vs. NHE), which was attributed to its enhanced surface area (due to the presence of small dendrite branches), extended broadband light absorption extending from UV to visible light regions, and the most efficient interfacial charge transfer as proven by electrochemical impedance spectroscopy (EIS) studies. Besides, the incident photon-to-current conversion efficiency and applied bias photon-to-current efficiency tests confirmed an improved spectral photoresponse of the heterojunction based photoanode, particularly towards the visible light spectrum. The results outline a promising synthesis route for building heterojunctions between visible light active and wide band gap semiconductors for the use as a highly efficient photoanodes in a PEC cell.</jats:p>