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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Singamaneni, Srikanth
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Topics
Publications (4/4 displayed)
- 2018Extreme Mechanical Behavior of Nacre-Mimetic Graphene-Oxide and Silk Nanocomposites.citations
- 2017Wood Graphene Oxide Composite for Highly Efficient Solar Steam Generation and Desalinationcitations
- 2016Adsorption Behavior of Silk Fibroin on Amphiphilic Graphene Oxidecitations
- 2012Gold nanorods as nanotransducers to monitor the growth and swelling of ultrathin polymer filmscitations
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article
Gold nanorods as nanotransducers to monitor the growth and swelling of ultrathin polymer films
Abstract
<p>In this work, we demonstrate that plasmonic nanostructures can be employed as nanoscale transducers to monitor the growth and phase transitions in ultrathin polymer films. In particular, gold nanorods with high refractive index sensitivity (150nm/refractive index unit (RIU)) were employed to probe the growth and swelling of polyelectrolyte multilayers (PEM). By comparing the wavelength shift and extinction intensity increase of the localized surface plasmon resonance (LSPR) of the gold nanorods coated with PEM in air and water, the swelling of PEM was estimated to be 26%±6%. The swelling was quantitatively confirmed with independent thickness measurement of PEM in dry and swollen states using AFM. The deployment of shape-controlled metal nanostructures with high refractive index sensitivity represents a novel and facile approach for monitoring the phase transition in polymers with nanoscale resolution.</p>