| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Czarnecki, Piotr
Adam Mickiewicz University in Poznań
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2022Above-room-temperature ferroelectricity and piezoelectric activity of dimethylglycinium-dimethylglycine chloridecitations
- 2012New ferroelectric: Bis-thiourea pyridinium bromide inclusion compoundcitations
- 2012Structures and phase transitions in a new ferroelectric-pyridinium chlorochromate-studied by X-ray diffraction, DSC and dielectric methodscitations
- 2010The neutron diffraction study, calorimetry and spontaneous polarization of pyridinium perrhenate at 350, 300 and 100Kcitations
- 2009Discovery of an intermediate phase in bis-thiourea pyridinium chloride inclusion compound.citations
- 2009Discovery of an intermediate phase in bis-thiourea pyridinium chloride inclusion compoundcitations
- 2008Redetermination of the structure and dielectric properties of bis(thiourea) pyridinium iodide - A new ferroelectric inclusion compoundcitations
- 2007Phase transitions in ferroelectric pyridinium periodide under high pressurecitations
- 2006Structure, phase transitions and dielectric properties of a new inclusion compound of bis-thiourea pyridinium nitrate saltcitations
- 2006Dielectric response of the relaxor ferroelectric Pb(Mg<inf>1/3</inf>Nb <inf>2/3</inf>)O<inf>3</inf> in the nonergodic state after a DC electric field is turned off
- 2005Decoupling of the order-disorder and displacive contributions to the phase transition in NH<inf>4</inf>H(ClH<inf>2</inf>CCOO)<inf>2</inf>citations
- 2005Compositional and pressure effects on the phase transition in ferroelectric NH<inf>4</inf>H(ClH<inf>2</inf>CCOO)<inf>2</inf>
- 2003Effect of hydrostatic pressure on the dielectric response of Pb(Mg 1/3Nb2/3)O3 relaxorcitations
- 2003The neutron diffraction study of pyridinium periodate at 352, 300 and 100 Kcitations
- 20012-5 pyrochlore relaxor ferroelectric Cd<inf>2</inf>Nb<inf>2</inf>O<inf>7</inf> and its Fe<sup>2+</sup>/Fe<sup>3+</sup> modificationscitations
- 2001Structure and dynamics of ferroelectric pyridinium periodatecitations
- 2000High pressure study of cation dynamics in pyridinium Perchloratecitations
- 2000Structure and dielectric properties of ferroelectric pyridinium perrhenate crystalscitations
Places of action
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article
Structure and dynamics of ferroelectric pyridinium periodate
Abstract
<p>The crystal and molecular structure of a new ferroelectric from the pyridinium salt group [C<sub>5</sub>H<sub>5</sub>NH]<sup>+</sup>IO<sub>4</sub><sup>-</sup> was determined by the x-ray diffraction method at 350, 300 and 100 K. The high temperature and intermediate phases are orthorhombic, while the low temperature phase is monoclinic, with the following sequences of space groups and continuous phase transitions: Cmcm→<sup>321K</sup> Cmc2<sub>1</sub>→<sup>210K</sup>C2. The two orthorhombic phases are isostructural with PyReO<sub>4</sub>, where the pyridinium cation is disordered and the periodate anion is ordered. The low temperature phase is well ordered. The intermediate and low temperature phases are ferroelectric. Measurements of spin-lattice relaxation time and complex permittivity have been performed for polycrystalline and monocrystalline samples as a function of pressure and temperature. The potential shape and heights of the energy barriers for cation reorientations in ferroelectric phases have been proposed. The complex permittivity measurements indicate the order-disorder character of the ferroelectric phase transition and continuous slowing of the cation dynamics with decreasing temperature.</p>