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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Sandeman, Susan
University of Brighton
in Cooperation with on an Cooperation-Score of 37%
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Publications (3/3 displayed)
- 2016Nano carriers for drug transport across the blood–brain barriercitations
- 2014Synthesis of the polymerizable room temperature ionic liquid AMPS – TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamidecitations
- 2006The in vitro adsorption of cytokines by polymer-pyrolysed carboncitations
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article
Synthesis of the polymerizable room temperature ionic liquid AMPS – TEA and superabsorbency for organic liquids of its copolymeric gels with acrylamide
Abstract
A polymerizable room temperature ionic liquid (RTIL), 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) - triethylamine (TEA), was synthesized by neutralization of AMPS with TEA in acetone followed by evaporation of the solvent under a reduced pressure at room temperature. The RTIL was characterized with fourier transform infrared spectroscopy, differential scanning calorimetry (DSC), and 1H NMR. Co-polymeric gels of the RTIL with acrylamide (AAm) were prepared by aqueous solution polymerization using N,N′-methylenebisacrylamide as a crosslinker, and ammonium persulfate as an initiator. Superabsorbency of the gels in aqueous and a series of organic liquids was investigated gravimetrically. DSC data showed that the glass transition temperature of AMPS - TEA was 59.4 °C. Poly (AMPS - TEA-co-AAm) gels exhibited superabsorbency in both water and a series of organic solvents. The mechanism for swelling in aqueous and organic media of the gels was critically discussed.