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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Imrie, Corrie
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2024A design approach to obtaining highly polar liquid crystal dimerscitations
- 2021Twist-Bend Nematic Glassescitations
- 2021Multiple Polar and Non-polar Nematic Phasescitations
- 2019Augmenting Bragg Reflection with Polymer-sustained Conical Helixcitations
- 2015New insights into the liquid crystal behaviour of hydrogen-bonded mixtures provided by temperature-dependent FTIR spectroscopycitations
- 2013Study of Structure Formation in Side-Chain Liquid Crystal Copolymers by Variable Temperature Fourier Transform Infrared Spectroscopycitations
- 2013Spectroscopic and thermal characterisation of the swelling behaviour of Nafion membranes in mixtures of water and methanolcitations
- 2013Characterization of Functionalized Side-Chain Liquid Crystal Methacrylates Containing Nonmesogenic Units by Dielectric Spectroscopycitations
- 2013A new polymer electrolyte based on a discotic liquid crystal triblock copolymercitations
- 2012Synthesis and characterisation of side chain liquid crystal copolymers containing sulfonic acid groupscitations
- 2011New insights from variable-temperature and variable-pressure studies into coupling and decoupling processes for ion transport in polymer electrolytes and glassescitations
- 2010Preparation and thermal characterisation of films containing liquid crystals in a cellulose acetate substrate for externally regulated applicationscitations
- 2007Liquid crystal dimers and higher oligomerscitations
- 2004Discotic side group liquid crystal polymer electrolytes
- 2003Application of complementary experimental techniques to characterization of the phase behavior of [C(16)mim][PF6] and [C(14)mim][PF6]citations
- 2001Highly non-linear liquid crystal tetramerscitations
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article
Discotic side group liquid crystal polymer electrolytes
Abstract
<p>The synthesis and characterization is reported of a novel discotic side group polymer based on a predominantly poly(ethylene oxide) backbone to which are attached triphenylene-based mesogenic groups via flexible spacers. The thermal and mechanical behavior of this polymer and its complex with lithium perchlorate are compared. The addition of salt increased both the glass transition temperature and clearing point of the host polymer. The temperature dependence of the ionic conductivity of the polymer-salt complex is reported and reveals that ionic conduction can occur in essentially solid-like liquid crystal polymer electrolytes. Ion transport in this material presumably involves assistance from local segmental motions of the backbone but does not rely upon long range cooperative motions.</p>