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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Lai, Romina
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (3/3 displayed)
- 2017Mechanosynthesis of coordination polymers based on dithiophosphato and dithiophosphonato NiII complexes and 1,4-di(3-pyridinyl)buta-1,3-diyne ligandcitations
- 2017Mechanosynthesis of coordination polymers based on dithiophosphato and dithiophosphonato NiIIcomplexes and 1,4-di(3-pyridinyl)buta-1,3-diyne ligandcitations
- 2016Coordination polymers and polygons using di-pyridyl-thiadiazole spacers and substituted phosphorodithioato NiII complexes: potential and limitations for inorganic crystal engineeringcitations
Places of action
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article
Mechanosynthesis of coordination polymers based on dithiophosphato and dithiophosphonato NiII complexes and 1,4-di(3-pyridinyl)buta-1,3-diyne ligand
Abstract
In recent decades the mechanosynthesis of Coordination Polymers (CPs) has consolidated as a powerful method for the formation of coordination bonds. The aim of this study regards the environmental friendly mechanosynthesis of coordination polymers by milling the neutral square planar NiII complexes [((MeO)2PS2)2Ni] (1), [((EtO)2PS2)2Ni] (2), [((MeO–C6H4)(MeO))PS2)2Ni] (3), [((MeO–C6H4)(EtO))PS2)2Ni] (4), with the organic ligand 1,4-di(3-pyridyl)buta-1,3-diyne (L). Using these substrates, several mechanosynthesis were performed via Net Grinding (NG) and Liquid Assisted Grinding (LAG) approaches. A mechanochemical trend concerning the general inverse correlation between melting point of reagents and reactivity has been observed, highlighting a possible mechanism for these reactions under mechanical conditions.