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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Poulis, Hans
Delft University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2022The influence of the surface roughness, creep and relaxation on the performance of elastomeric liners for sustainable glass bottle closurescitations
- 2021The influence of grit blasting and UV/Ozone treatments on Ti-Ti adhesive bonds and their durability after sol-gel and primer applicationcitations
- 2021The photostability and peel strength of ethylene butyl acrylate copolymer blends for use in conservation of cultural heritagecitations
- 2020Influence of moisture and CO2 on the material behavior of thermoplastic elastomers for beer bottle closurescitations
- 2020Enhanced Interface Adhesion by Novel Eco-Epoxy Adhesives Based on the Modified Tannic Acid on Al and CFRP Adherendscitations
- 2020The Influence of Loading, Temperature and Relative Humidity on Adhesives for Canvas Liningcitations
- 2020Improving the adhesion strength of polymers: effect of surface treatmentscitations
- 2017Laboratory strength testing of pine wood and birch bark adhesives: a first study of the material properties of pitchcitations
- 2016Lap Shear and Impact Testing of Ochre and Beeswax in Experimental Middle Stone Age Compound Adhesivescitations
Places of action
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article
The photostability and peel strength of ethylene butyl acrylate copolymer blends for use in conservation of cultural heritage
Abstract
Materials, both natural and synthetic, are used as adhesives or consolidants during the conservation of cultural objects. However, few adhesives have been formulated specifically for the needs of cultural heritage. This article describes a study of the stability of ethylene butyl acrylate copolymers as well as blends of these polymers with low molecular weight resins, which may be used as consolidating adhesives for flaking and fragile paint layers. The materials were aged under simulated museum conditions. Fourier-transform infrared spectroscopy and size exclusion chromatography were used to analyze changes in chemical structure and molecular weight distribution, respectively. The degree of degradation was found to be dependent on the specific blend composition. With the addition of a hindered amine light stabilizer, minimal changes occurred in the molecular weight distribution and no loss in polymer solubility were noted. Therefore, it is suggested to incorporate a stabilizer into ethylene butyl acrylate polymer blends to extend their life and safe use in cultural heritage. Differential scanning calorimetry was employed to investigate the miscibility of the binary blends and the temperature window of their application. Furthermore, adhesive peel strength for the individual components and the binary mixtures revealed values comparable to that of Paraloid™ B-72, a frequently used consolidant. Consolidation tests on the blends were done by professional conservators on mock up and dummy paintings.